The Fe-bearing hypereutectic Al-Si alloys with/without Cr/(Cr+Mn) addition have been prepared by Spray Forming (SF) process. With 2 wt.% Cr addition, the short-rod b-Al 5 FeSi phase in sprayformed Al-25Si-5Fe-3Cu (wt.%, denoted as 3C) alloy can be substituted by particulate aAl(Fe,Cr)Si phase with sizes less than 5 -6 lm. But small quantity of blocky b-Al 5 (Fe,Cr)Si phase still appears in Cr-added hypereutectic Al-Si alloy. When (2Cr+1Mn) (wt.%) are added simultaneously into 3C alloy, almost all the short-rod b-Al 5 FeSi phase or blocky b-Al 5 (Fe,Cr)Si phase disappear, instead, the a-Al(Fe,Cr,Mn)Si phase become the only Fe-bearing phase. During heat treatments, the other two spray-formed hypereutectic Al-Si alloys (besides SF-3C alloy) are thermodynamically stable for the appearance of high thermodynamically stable particulate aAl(Fe,Cr)Si/a-Al(Fe,Cr,Mn)Si phase. Also the phase transformation occurred during the heating/ cooling process of the present hypereutectic Al-Si alloys are investigated and the mechanism of microstructural formation of the spray-formed alloys are discussed.Keywords: Spray Forming / hypereutectic Al-Si alloy / microstructure / thermal stability / phase transformation / Schlüsselwörter: Sprühkompaktieren / hypereutektische Al-Si-Lebierung / thermische Stabilität / Phasenumwandlung /