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Cited by 33 publications
(12 citation statements)
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“…The proposed scheme of bleaching of methyl red by ICl is similar to the bleaching of colour of methyl orange by chlorine or bromine. 23) In the case of chlorine (stronger oxidizing agent compared to bromine) the bleaching is carried upto 70% by oxidation of azo linkage and 30% by aromatic ring substitution.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The proposed scheme of bleaching of methyl red by ICl is similar to the bleaching of colour of methyl orange by chlorine or bromine. 23) In the case of chlorine (stronger oxidizing agent compared to bromine) the bleaching is carried upto 70% by oxidation of azo linkage and 30% by aromatic ring substitution.…”
Section: Resultsmentioning
confidence: 99%
“…This was clearly established by the synthesis and spectral characterization of relevant compounds. 23) ICl is a good iodinating agent compared to iodine. 24) Iodination of dyes like dichlorofluorescein and thymol blue with ICl were used for the spectrophotometric determination of ascorbic acid 25) and sulphur dioxide.…”
Section: Resultsmentioning
confidence: 99%
“…These thermodynamics predict that at equilibrium the >100‐fold excess of chlorite should oxidize >70 % of the starting Mn III to OMn V O. The intermediacy of hypochlorite generated from this step was indicated by the diagnostic chlorination of added methyl orange,10 while sodium chlorite alone gave no detectable chlorination under these conditions (Supporting Information).…”
Section: Methodsmentioning
confidence: 99%
“…The reported DG for oxo-transfer from ClO 2 À is only slightly lower than that of hypobromite ion (DDG 298 = 17 kJ mol À1 ). The intermediacy of hypochlorite generated from this step was indicated by the diagnostic chlorination of added methyl orange, [10] while sodium chlorite alone gave no detectable chlorination under these conditions (Supporting Information). [5] At pH 6.8, the reduction potential for the ClO 2 À / ClO À couple is only slightly higher than that of the oxoMn V / Mn III couple (DE = À0.06 V), corresponding to a K eq = 10 À2.0 for oxo-transfer from chlorite to Mn III (Supporting Information).…”
Section: Thomas P Umile and John T Groves*mentioning
confidence: 99%