Silicon Oxycarbide (SiOC)-Supported Ionic Liquids: Heterogeneous Catalysts for Cyclic Carbonate Formation

Abstract

Silicon oxycarbides (SiOCs) impregnated with tetrabutylammonium halides (TBAX) were investigated as an alternative to silica-based supported ionic liquid phases for the production of bio-based cyclic carbonates derived from limonene and linseed oil. The support materials and the supported ionic liquid phases (SILPs) were characterized via Fourier transform infrared spectroscopy, thermogravimetric analysis, nitrogen adsorption, X-ray photoelectron spectroscopy, microscopy, and solvent adsorption. The silicon oxycarbide supports were pyrolyzed at 300−900 °C prior to being coated with different tetrabutylammonium halides and further used as heterogeneous catalysts for the formation of cyclic carbonates in batch mode. Excellent selectivities of 97−100% and yields of 53−62% were obtained with tetrabutylammonium chloride supported on the silicon oxycarbides. For comparison, the catalytic performance of commonly employed silica-supported ionic liquids was investigated under the same conditions. The silica-supported species triggered the formation of a diol as a byproduct, leading to a lower selectivity of 87% and a lower yield of 48%. Ultimately, macroporous monolithic SiOC-SILPs with suitable permeability characteristics (k 1 = 10 −11 m 2 ) were produced via photopolymerization-assisted solidification templating and applied for the selective and continuous production of limonene carbonate with supercritical carbon dioxide as the reagent and sole solvent. Constant product output over 48 h without concurrent catalyst leaching was achieved.