Significance and experimental determination of stoichiometric number

Horiuti, Juro

doi:10.1016/0021-9517(62)90048-9

Cited by 18 publications

(18 citation statements)

References 4 publications

(18 reference statements)

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“…The plot of ln{q} versus time, 19 (Fig. 4.8) gives a straight line with a slope of (k 1 + k 2 ) and the point of intersection with the ordinate…”

Section: System Of Reactions Kinetically Characterized By Several Ratmentioning

confidence: 99%

“…The overallheat of the reaction is due to (4.44): 19 In the case of negative q-values ln{|q(t)|} must be plotted; the procedure of interpretation is similar. 20 ÀΔH λ ð Þ results also from the total amount of heat released according to…”

Section: System Of Reactions Kinetically Characterized By Several Ratmentioning

confidence: 99%

“…In such cases, one must first elaborate the system of reversible elementary reactions, which form the basis of the reversible overall process [19,34]. If it becomes evident that one elementary reaction is dominant for the rate of the overall process, a "stoichiometric correction number" v can be stated.…”

Section: Estimating the Equilibrium Constant By Thermokinetic Measurementioning

confidence: 99%

“…19 Temporal course of signal T 2F of temperature sensor after injection of triazine A in aqueous solution of naphthylamine sulphonic acid B, non-isothermal, isoperibolic, discontinuous reaction…”

mentioning

confidence: 99%

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Bench Scale Calorimetry in Chemical Reaction Kinetics

Litz¹

2015

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“…The plot of ln{q} versus time, 19 (Fig. 4.8) gives a straight line with a slope of (k 1 + k 2 ) and the point of intersection with the ordinate…”

Section: System Of Reactions Kinetically Characterized By Several Ratmentioning

confidence: 99%

Section: System Of Reactions Kinetically Characterized By Several Ratmentioning

confidence: 99%

Section: Estimating the Equilibrium Constant By Thermokinetic Measurementioning

confidence: 99%

mentioning

confidence: 99%

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Bench Scale Calorimetry in Chemical Reaction Kinetics

Litz¹

2015

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“…13 and his later publications. 8,10 In Russia, the results obtained by Horiuti and Enomoto 3 have become known primarily from Ref. 13, and accordingly the corresponding general prescriptions are referred to as the Boreskov-Horiuti rules.…”

Section: Introductionmentioning

confidence: 99%

Boreskov–horiuti–enomoto Rules for Reversible Heterogeneous Catalytic Reactions

Zhdanov

2007

Surf. Rev. Lett.

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In the middle of the previous century, G. K. Boreskov, and J. Horiuti and S. Enomoto independently showed that for reversible reactions, running via a one-route mechanism with a ratelimiting step, there exist general relationships between the reaction rates in the forward and backward directions and also between the corresponding apparent activation energies and reaction heat. Their treatments are formally applicable to gas-and liquid-phase reactions and also to heterogeneous catalytic reactions (HCR) occurring in an ideal overlayer adsorbed on a uniform surface. In reality, HCR often run on heterogeneous surfaces, and the HCR kinetics are complicated by adsorbate-adsorbate lateral interactions. I explicitly demonstrate that in such situations the Boreskov-Horiuti-Enomoto rules are applicable as well.

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Significance and experimental determination of stoichiometric number

Cited by 18 publications

References 4 publications

Bench Scale Calorimetry in Chemical Reaction Kinetics

Bench Scale Calorimetry in Chemical Reaction Kinetics

Boreskov–horiuti–enomoto Rules for Reversible Heterogeneous Catalytic Reactions

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