volume 159, issue 11, P3251-3263 2012
DOI: 10.1016/j.combustflame.2012.06.012
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King-Yiu Lam, Wei Ren, Zekai Hong, David F. Davidson, Ronald K. Hanson

Abstract: a b s t r a c tHigh-temperature 3-pentanone pyrolysis and oxidation studies were performed behind reflected shock waves using laser-based species time-history measurements (3-pentanone, CH 3 , CO, C 2 H 4 , OH and H 2 O) and ignition delay time measurements. The overall 3-pentanone decomposition rate coefficient was inferred from the measured 3-pentanone and CH 3 time-histories during pyrolysis at temperatures of 1070-1530 K and a pressure of 1.6 atm., and yielded a mathematical expression for k tot = 4.383 Â…

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