volume 60, issue 4, P1607-1618 1974
DOI: 10.1063/1.1681238
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D. E. O'Reilly

Abstract: A new model for liquid water is presented. As a first approximation (A) the liquid is considered as a quasi-hard-sphere fluid and the scaled particle theory is employed to calculate the work (w) required to create a vacancy of molecular dimension using the observed density of water. In the second approximation (B) a quasilattice model is invoked which is based on the Ice VII structure and the density and isothermal compressibility of water are computed using the values of w calculated in approximation A. A fi…

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