Self-assembly of three hetero- and homopolynuclear cyanide bridged complexes of FeII–CuI and CuI: hydrothermal syntheses, structural characterization and properties

Mao, Hongyan; Zhang, Changzheng; Xu, Chen; Zhang, Hongyun; Shen, Xiaofeng; Wu, Ben‐Lai; Zhu, Yinian; Wu, Qing‐An; Wang, Hui

doi:10.1016/j.ica.2004.12.045

Cited by 23 publications

(15 citation statements)

References 35 publications

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“…Temperature will also increase the oxidation potential. Reduction of Fe(III) to Fe(II) under hydrothermal condition has been reported previously [30][31][32]. As for the protonation of BPTC 4-in [Fe(phen) 3 ] Á (H 3 BPTC) 2 , this can be explained by the reduction of Fe(III) to Fe(II) which will increase the acidity.…”

Section: Resultsmentioning

confidence: 76%

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Zhu

Zhang

Shao

et al. 2008

Transition Met Chem

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Section: Resultsmentioning

confidence: 76%

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Zhu

Zhang

Shao

et al. 2008

Transition Met Chem

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“…Three novel Ag(I)-cyanide coordination polymers were successfully prepared and structurally characterized. 6 ] acts as a cyanide source which can slowly release cyanide upon heat treatment [9,20].…”

Section: Accepted Manuscriptmentioning

confidence: 99%

Three Ag(I)–cyanide coordination polymers with metal bonds tuned by N-heterocyclic ligands

Shao

Wang

et al. 2015

Inorganic Chemistry Communications

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“…For related crystal structures, see: Chesnut & Zubieta (1998); He et al (2005); Mao et al (2005); Yan et al (2006).…”

Section: Related Literaturementioning

confidence: 99%

Poly[(2,2′-bipyridyl)-μ₃-cyanido-di-μ₂-cyanido-dicopper(I,II)]

Rui

Mai-xi

2007

Acta Cryst E

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The title compound, [Cu2(CN)3(C10H8N2)]n, crystallizes as a cyanido‐bridged three‐dimensional polymeric structure, where there coexist CuI and CuII ions along with μ3‐ and μ2‐bridging cyanide groups. Each CuI ion is coordinated by four C atoms [Cu—C = 1.956 (3)–2.147 (3) Å] from two μ3‐ and two μ2‐cyanide groups in a tetrahedral environment. The CuII ion is coordinated by two N atoms from the 2,2′‐bipyridyl ligand and three N atoms from one μ3‐ and two μ2‐cyanide groups in a square‐pyramidal geometry [Cu—N = 1.967 (3)–2.183 (3) Å]. The CuI ions are paired by two C atoms from two cyanide groups into a dinuclear unit with a short CuI...CuI distance of 2.5398 (8) Å. Each dinuclear unit links six CuII ions by four μ2‐ and two μ3‐cyanide groups to form a 4,6‐connected framework, with CuI...CuII separations ranging from 4.864 (4) to 5.252 (4) Å.

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Self-assembly of three hetero- and homopolynuclear cyanide bridged complexes of FeII–CuI and CuI: hydrothermal syntheses, structural characterization and properties

Cited by 23 publications

References 35 publications

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Three Ag(I)–cyanide coordination polymers with metal bonds tuned by N-heterocyclic ligands

Poly[(2,2′-bipyridyl)-μ₃-cyanido-di-μ₂-cyanido-dicopper(I,II)]

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Self-assembly of three hetero- and homopolynuclear cyanide bridged complexes of FeII–CuI and CuI: hydrothermal syntheses, structural characterization and properties

Cited by 23 publications

References 35 publications

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Monomeric and polymeric structures derived from 3,3′,4,4′-biphenyltetracarboxylic acid, phenanthroline and metal ions

Three Ag(I)–cyanide coordination polymers with metal bonds tuned by N-heterocyclic ligands

Poly[(2,2′-bipyridyl)-μ3-cyanido-di-μ2-cyanido-dicopper(I,II)]

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Product

Resources

About

Poly[(2,2′-bipyridyl)-μ₃-cyanido-di-μ₂-cyanido-dicopper(I,II)]