volume 2019, issue 34, P5916-5924 2019
DOI: 10.1002/ejoc.201900988
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Abstract: A linear synthesis of o‐terphenyl derivatives has been delineated using ring closing metathesis (RCM) as the key step. In this approach, benzil derivatives upon allyl Grignard addition provides diphenyl‐1,2‐diallyl dihydroxy derivatives which undergo ring closing metathesis to afford tetrahydro terphenyl derivatives. Aromatization‐driven dehydration then leads to a diverse set of electron rich and electron deficient o‐terphenyls. Furthermore, oxidative coupling of electron rich o‐terphenyls provides the corre…

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