Regioselective anodic α-methoxylation of 2-oxazolidinone on boron doped diamond in acidic methanol medium

Saravanan, K.; Selvamani, V.; Kulangiappar, K.; Velayutham, D.; Suryanarayanan, V.

doi:10.1016/j.elecom.2012.12.002

Cited by 15 publications

(7 citation statements)

References 9 publications

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“…Oxazolidinones belong to a group of antimicrobial agents that are effective against Gram-positive pathogenic bacteria. 41 Saravanan et al 42 reported a methoxylation of a 2-oxazolidinone using boron doped diamond (BDD) or graphite as the anode (Scheme 2). Higher yields were obtained for BDD, with a maximum value of 88% obtained for a current density of 50 mA cm −2 .…”

Section: Electrochemical Reactions For Organicmentioning

confidence: 99%

Organic Electrosynthesis: From Laboratorial Practice to Industrial Applications

Cardoso

Šljukić

Santos

et al. 2017

Org. Process Res. Dev.

195

144

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Organic electrosynthesis has received great attention as a powerful green tool for synthesis, affording less waste production, less chemicals spent, and often fewer reaction steps than conventional methods. Functional group interconversion and C−C bond generation by imposition of a proper electrode potential is what lies behind organic electrosynthesis processes. Paired electrochemical reactions, indirect electrosynthesis, electrochemical microreactors, and the use of ionic liquids are some of the highlighted means that contribute to optimization of the overall process. Necessity to use specific organic solvents combined with supporting electrolytes is one of the main limitations to be overcome to make the electrochemical process more economically feasible when compared to nonelectrochemical processes. Numerous examples from the bench scale to industrial routes such as adiponitrile, substituted benzaldehydes, anthraquinone, fluorinated products, and succinic acid production are well described throughout this review.

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Section: Electrochemical Reactions For Organicmentioning

confidence: 99%

Organic Electrosynthesis: From Laboratorial Practice to Industrial Applications

Cardoso

Šljukić

Santos

et al. 2017

Org. Process Res. Dev.

195

144

View full text Add to dashboard Cite

show abstract

“…8,10,11 Existing routes rely on the use of toxic MOM-Cl or formaldehyde dimethyl acetal, 10 however, Suryanarayanan and co-workers have shown that methoxymethyl ether functionality can be introduced into 2-oxazolidinones by means of anodic oxidation using either boron doped diamond (BDD) or carbon graphite (C gr ) electrodes (Scheme 2). 22 This has been further complimented by work by both Waldvogel 11 and Lam 8,10 who have further demonstrated the ability to introduce MOM-ether functionality into organic systems using green reagents under ambient conditions, the latter of which further showed how common problems such as the overoxidation of aromatic derivatives could be overcome through the use of flowelectrochemistry. 8 O The use of carboxylates in electrosynthesis is well established.…”

Section: Reactivity At the Anodementioning

confidence: 93%

Organic electrosynthesis: from academia to industry

et al. 2020

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“…In this case, it is very important that the substance adsorbed being removed with an appropriate solvent, and more than that, this solvent must have properties that enable it to be used in electrochemical oxidation processes. As far as we know, electrolysis performed in non-aqueous media is a new issue and there is just a few works in the literature (Ayata et al, 2013;Saravanan et al, 2013). Other works include electro reduction (Farzinnejad et al, 2005;Wain et al, 2006;Chanique et al, 2013) or the organic synthesis (Inprakhon et al, 2017;Suresh et al, 2018) were studied.…”

Section: Introductionmentioning

confidence: 99%