Recent trends in the direct oxyphosphorylation of C–C multiple bonds

Abstract

Due to the wide importance of β-phosphorylated ketones as key building-blocks in the fabrication of various pharmaceutically active organophosphorus compounds, finding new and truly efficient methods for their preparation.

Direct selenosulfonylation of unsaturated compounds: a review

“…20 Since several important and striking advantages on this difunctionalization reaction have occurred during the past several years, it seems it is an appropriate time to summarize those developments. In connection with our interest on difunctionlization reactions, 21 organosulfur chemistry 22 and modern organic synthesis, 23 herein, we intend to summarize the literature reports on the selenosulfonylation of unsaturated compounds from 1980 till date. For clarity, the topic is divided into three major sections.…”

Green-inspired synthetic drives for organophosphorus compounds under solvent-free conditions

“…[1][2][3][4][5][6][7][8][9][10][11] They offer immense possibilities for structural, synthetic, and mechanistic studies. [12][13][14][15] Therefore, synthetic chemists are continuously searching for novel series of diversely functionalized organophosphorus molecules. [16][17][18][19][20][21][22] As part of their synthetic endeavors, designing and developing methodologies following green-chemistry principles have become routine.…”

Progress and recent trends in the direct selenocyanation of (hetero)aromatic C–H bonds

“…Since a number of remarkable developments in this attractive research field have taken place during the past few years, seems it is an appropriate time to summarize those advances. In continuation of our interest on the direct functionalization of C–H bonds 18–21 and modern organic synthesis, 22 herein, we will try to provide a comprehensive overview of the synthesis of selenocyanated arenes and heteroarenes through the direct selenocyanation of (hetero)aryl Csp 2 –H bonds ( Fig. 1 ) with an aim to inspire scientists to conduct more research in the field and develop new and creative synthetic access routes to biologically active organoselenocyanates and other important organoselenium compounds.…”