“…With the burgeoning focus on the potential applications of metal–organic frameworks (MOFs) in multifarious fields recently, Prussian blue (PB) and Prussian blue analogues (PBAs), an extremely easily available subcategory among 20,000 MOFs, re-enter into people’s horizons. − Despite the span of PB over three centuries, just over the past one and a half years from 2021 to October 2022, there have been 29 published reviews recorded in Web of Science on the synthesis techniques and applications of PB/PBAs mainly related to energy storage and conversion, − catalysis, − and electrochemical sensors. , In particular, because of their advantageous features including the low-cost, environmental benignity, open framework, compositional control, excellent redox activity, high cycling stability, and highly reversible phase transitions of PB/PBAs-based electrodes, PB/PBAs have been extensively explored as promising active materials in electrochemical applications such as energy storage devices, electrocatalysis, and sensors in the last decade. ,,,− Nevertheless, the poor conductivity of PB/PBAs with cyanide bridges frequently frustrates their practicability in the electrochemistry-related applications, and compositing highly conductive materials such as carbon materials is the simplest way for facilitating electron transfer and enhancing electrochemical kinetics. , …”