Recent advances in designing solid-state electrolytes to reduce the working temperature of lithium batteries

Yao, Zhicheng; Wang, Yutong; Wan, Shuang; Ma, Weiting; Rong, Junfeng; Xiao, Ying; Hou, Guolin; Chen, Shimou

doi:10.1039/d3qm00662j

Cited by 6 publications

(8 citation statements)

References 165 publications

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“…A primary challenge in using lithium-metal anodes is the formation of lithium dendrites during cycling, leading to potential short circuits and battery failure, as noted in A primary challenge in using lithium-metal anodes is the formation of lithium dendrites during cycling, leading to potential short circuits and battery failure, as noted in ref. [166]. This dendritic growth, along with chemical and electrochemical instability and chemomechanical expansion, creates significant barriers to the commercialization of SSBs.…”

Section: Anode Materials Selection For Ssbsmentioning

confidence: 99%

“…This dendritic growth, along with chemical and electrochemical instability and chemomechanical expansion, creates significant barriers to the commercialization of SSBs. To address these issues, Yao and colleagues [166] concentrated their research on designing solid-state electrolytes that operate at reduced temperatures. Their findings suggest that lower operational temperatures in SSBs can greatly improve the stability and effectiveness of lithium-metal anodes, thereby reducing the risks associated with dendrite formation and other instabilities.…”

Section: Anode Materials Selection For Ssbsmentioning

confidence: 99%

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Advancements and Challenges in Solid-State Battery Technology: An In-Depth Review of Solid Electrolytes and Anode Innovations

Machín,

Morant,

Márquez

2024

Batteries

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The primary goal of this review is to provide a comprehensive overview of the state-of-the-art in solid-state batteries (SSBs), with a focus on recent advancements in solid electrolytes and anodes. The paper begins with a background on the evolution from liquid electrolyte lithium-ion batteries to advanced SSBs, highlighting their enhanced safety and energy density. It addresses the increasing demand for efficient, safe energy storage in applications like electric vehicles and portable electronics. A major part of the paper analyzes solid electrolytes, key to SSB technology. It classifies solid electrolytes as polymer-based, oxide-based, and sulfide-based, discussing their distinct properties and application suitability. The review also covers advancements in anode materials for SSBs, exploring materials like lithium metal, silicon, and intermetallic compounds, focusing on their capacity, durability, and compatibility with solid electrolytes. It addresses challenges in integrating these anode materials, like the interface stability and lithium dendrite growth. This review includes a discussion on the latest analytical techniques, experimental studies, and computational models to understand and improve the anode–solid electrolyte interface. These are crucial for tackling interfacial resistance and ensuring SSBs’ long-term stability and efficiency. Concluding, the paper suggests future research and development directions, highlighting SSBs’ potential in revolutionizing energy storage technologies. This review serves as a vital resource for academics, researchers, and industry professionals in advanced battery technology development. It offers a detailed overview of materials and technologies shaping SSBs’ future, providing insights into current challenges and potential solutions in this rapidly evolving field.

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Section: Anode Materials Selection For Ssbsmentioning

confidence: 99%

Section: Anode Materials Selection For Ssbsmentioning

confidence: 99%

Advancements and Challenges in Solid-State Battery Technology: An In-Depth Review of Solid Electrolytes and Anode Innovations

Machín,

Morant,

Márquez

2024

Batteries

View full text Add to dashboard Cite

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“…1) To improve the low-temperature conductivity of the electrolyte by optimizing the composition of the solvent and using new electrolyte salts; 2) To use new additives to increase the conductivity of lithium ions at low temperatures. [36] In 2003, Yuriy et al [37] reported a new generation of lithiumsulfur rechargeable batteries based on specially designed electrolytes. The extraordinary experimental data of LiÀ S batteries in the low-temperature performance was worth noting.…”

Section: Electrolytementioning

confidence: 99%

Design of Wide‐Temperature Lithium‐Sulfur Batteries

Yang,

Zhao,

et al. 2024

Batteries & Supercaps

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In electrochemical energy storage (EES), lithium‐sulfur (Li‐S) batteries have recently gained recognition for their exceptional theoretical specific capacity, making them stand out among a wide range of cutting‐edge energy storage technologies. While Li‐S batteries demonstrate a long cycle life under regular conditions, expanding their application scenarios is crucial for their future development. Specifically, ensuring stable battery operation in extreme temperature environments, such as below 0°C and above 60°C, becomes paramount. Thus, this review aims to summarize the recent progress of Li‐S batteries in extreme temperature ranges and analyze the processability of critical materials within these batteries at extreme temperatures. Ultimately, this review presents insights and potential prospects for Li‐S battery systems operating within a wide temperature range, contributing to advancing energy storage devices capable of functioning across various temperatures.

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“…Generally, LIBs used in electric vehicles and wearable portable electronic devices typically operate at temperatures between −20 and 40 °C . In particular cases, there are some ultralow temperature application scenarios below −30 °C, such as ultralow temperature electric vehicles in variable climates, polar scientific expedition, military equipment exposed to ultralow temperature, etc., , which pose increasingly severe challenges to the operation of batteries. , In ultralow temperature situation, the conduction of lithium ions in LIBs is severely hindered, resulting in a significant decrease in performance.…”

Section: Introductionmentioning

confidence: 99%

Toward Enhancing Low Temperature Performances of Lithium-Ion Transport for Metal–Organic Framework-Based Solid-State Electrolyte: Nanostructure Engineering or Crystal Morphology Controlling

Wang,

Jin,

Shi

et al. 2024

ACS Appl. Mater. Interfaces

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Metal−organic frameworks (MOFs) have emerged as attractive candidates for Li + conducting electrolytes due to their regular channels and controllable morphology, making their presence prominent in the field of solid-state lithium batteries. However, most MOF-based electrolytes are researched at or near room temperature, which poses a challenge to their practical applications at low temperatures. Herein, a thin layer flower-shaped 2D Cu-MOF (CuBDC-10)-based solid-state electrolytes (SSEs) for lithium-ion batteries (LIBs) are developed for facilitating Li + transport at lower temperatures, which achieve an ion conductivity of 10 −4 S cm −1 at −30 °C. The CuBDC-10-based SSE exhibits outstanding ionic conductivity over a wide temperature range of −40 to 100 °C (0.073−3.68 × 10 −3 S cm −1 ). This work provides strategies for exploring MOF-based SSEs with high ionic transport performances at low temperatures.

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Recent advances in designing solid-state electrolytes to reduce the working temperature of lithium batteries

Abstract: Although lithium-ion battery (LIB) has excellent performance, it has some defects such as poor safety performance and low energy density. Solid-state battery (SSB) is widely concerned because of its intrinsically...

Cited by 6 publications

References 165 publications

Advancements and Challenges in Solid-State Battery Technology: An In-Depth Review of Solid Electrolytes and Anode Innovations

Advancements and Challenges in Solid-State Battery Technology: An In-Depth Review of Solid Electrolytes and Anode Innovations

Design of Wide‐Temperature Lithium‐Sulfur Batteries

Toward Enhancing Low Temperature Performances of Lithium-Ion Transport for Metal–Organic Framework-Based Solid-State Electrolyte: Nanostructure Engineering or Crystal Morphology Controlling

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