Abstract:The synthesis, spectroscopic characterization and crystal structures of new C-nitrosoaryl complexes of iridium(III) and rhodium ( (8a)]. All new compounds were characterized by their melting points, NMR, IR and mass spectra as well as in selected cases by UV/Vis spectroscopy. The X-ray structure analyses revealed a slightly distorted pseudo-octahedral configuration ("three-legged pianostool") and σ -N coordination of the C-nitroso ligand.
Nitrosoarenes (ArNOs) are toxic metabolic intermediates that bind to heme proteins to inhibit their functions. Although much of their biological functions involve coordination to the Fe centers of hemes, the...
Nitrosoarenes (ArNOs) are toxic metabolic intermediates that bind to heme proteins to inhibit their functions. Although much of their biological functions involve coordination to the Fe centers of hemes, the...
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