Reactions of bis(isopropylxanthato)nickel(II) with nitrogen-donor ligands—II

Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

“…74°), which are somewhat narrower than those typically observed in nickel(II) dithiocarbamates such as [Ni(S 2 CNMe n Bu) 2 ] (79.2°) . The remaining bond lengths and angles are entirely typical of those observed in previous structurally characterized nickel xanthate complexes, − such as the similarly six-coordinate bis( O -benzylxanthate) complex [Ni(S 2 COCH 2 Ph) 2 (NC 5 H 3 -Me-3) 2 ], with essentially invariant Ni−S bond distances.…”

Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

“…74°), which are somewhat narrower than those typically observed in nickel(II) dithiocarbamates such as [Ni(S 2 CNMe n Bu) 2 ] (79.2°) . The remaining bond lengths and angles are entirely typical of those observed in previous structurally characterized nickel xanthate complexes, − such as the similarly six-coordinate bis( O -benzylxanthate) complex [Ni(S 2 COCH 2 Ph) 2 (NC 5 H 3 -Me-3) 2 ], with essentially invariant Ni−S bond distances.…”

Crystal structure of bis(3-bromopyridine-κN)bis(O-ethyl dithiocarbonato-κ2S,S′)nickel(II)

“…Xanthates as ligands have been investigated extensively due to their coordination behaviour (Haiduc et al, 1995), thereby showing monodentate and/or bidentate coordination modes (Xiong et al, 1997;Trá vnícek et al, 1995). Xanthates have also found uses as antitumour agents and in the treatment of Alzheimer's disease (Orts et al, 2002;Larsson & Ö berg, 2011).…”

Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

“…74°), which are somewhat narrower than those typically observed in nickel(II) dithiocarbamates such as [Ni(S 2 CNMe n Bu) 2 ] (79.2°) . The remaining bond lengths and angles are entirely typical of those observed in previous structurally characterized nickel xanthate complexes, − such as the similarly six-coordinate bis( O -benzylxanthate) complex [Ni(S 2 COCH 2 Ph) 2 (NC 5 H 3 -Me-3) 2 ], with essentially invariant Ni−S bond distances.…”

Crystal structure of bis(3-bromopyridine-κN)bis(O-ethyl dithiocarbonato-κ2S,S′)nickel(II)

“…Xanthates as ligands have been investigated extensively due to their coordination behaviour (Haiduc et al, 1995), thereby showing monodentate and/or bidentate coordination modes (Xiong et al, 1997;Trá vnícek et al, 1995). Xanthates have also found uses as antitumour agents and in the treatment of Alzheimer's disease (Orts et al, 2002;Larsson & Ö berg, 2011).…”

Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

“…74°), which are somewhat narrower than those typically observed in nickel(II) dithiocarbamates such as [Ni(S 2 CNMe n Bu) 2 ] (79.2°) . The remaining bond lengths and angles are entirely typical of those observed in previous structurally characterized nickel xanthate complexes, − such as the similarly six-coordinate bis( O -benzylxanthate) complex [Ni(S 2 COCH 2 Ph) 2 (NC 5 H 3 -Me-3) 2 ], with essentially invariant Ni−S bond distances.…”

Crystal structure of bis(3-bromopyridine-κN)bis(O-ethyl dithiocarbonato-κ2S,S′)nickel(II)

“…Xanthates as ligands have been investigated extensively due to their coordination behaviour (Haiduc et al, 1995), thereby showing monodentate and/or bidentate coordination modes (Xiong et al, 1997;Trá vnícek et al, 1995). Xanthates have also found uses as antitumour agents and in the treatment of Alzheimer's disease (Orts et al, 2002;Larsson & Ö berg, 2011).…”