Point defects, during e−h recombination, are a key factor in impacting optoelectronic device performance. Using nonadiabatic molecular dynamics (NAMD), here we investigate the nonradiative recombination of pristine, missing atom defects, including phosphorus vacancies (V P ) and phosphorus and boron vacancies (V BP ), and atom substitution defects, containing boron on the phosphorus site (B P ) and phosphorus on the boron site (P B ) of 2D monolayer hexagonal boron phosphide (h-BP). Carrier dynamics in the pristine h-BP and the defect engineered systems reveal that atom substitution defects B P and P B can suppress e−h nonradiative recombination. This is caused by the introduction of several lowfrequency phonons in defect states. Electron−phonon coupling between the electronic state and these low-frequency phonons shortens the decoherence time and the nonadiabatic coupling. Also, the atom substitution systems with one defect state introduce fewer carrier recombination channels. Such a mechanism can be extended to other 2D materials with the same structure as h-BP.