Pt-based nanocrystals with a three-dimensional (3D) branched
structure
represent a class of the most efficient catalysts for the methanol
oxidation reaction because of their large accessible surfaces and
high atomic utilization. Herein, nanoscale PtCuMn hexapods (HPDs)
have been synthesized by a facile one-pot solvent method. Strikingly,
the as-synthesized HPDs each contain a rhombic dodecahedral host and
six nanopods protruding from its ⟨100⟩ vertices. Evolution
experiments demonstrate that four stages are responsible for formation
of the HPDs: the preferential formation of Cu-enriched nuclei, the
galvanic substitution reaction between Cu-enriched nuclei and a Pt
precursor, the selective growth of Pt, and the deposition of Pt, Cu,
and Mn. Moreover, the morphology of the HPDs can be tuned by adjusting
the dosage of cetyltrimethylammonium bromide because of its ability
to affect the size of the preformed Cu-enriched nuclei and the rate
of the galvanic substitution reaction during the synthesis. For methanol
electrocatalysis, the PtCuMn HPDs exhibit substantially enhanced electrocatalytic
activity and durability in comparison with the commercial Pt/C catalyst.
It is expected that this work may provide an idea for the facile synthesis
of Pt-based catalysts with high efficiency and stability.