1959
DOI: 10.1021/j150581a008
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Abstract: A study has been made of the behavior of pure iron, immersed in solutions of ferrous and ferric perchlorates, using radioactive iron ions as tracer. The results indicate that exchange in depth is negligible at room temperature and that most, if not all, of the activity acquired by the metal is incorporated in solid corrosion products. Dichromate reduces the rate of dissolution of the metal in Fe(C104)3, but activity is picked up in a corrosion film. Cathodic polarization also inhibits dissolution in Fe( CICWs … Show more

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Cited by 4 publications
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“…Iron (12) Iron seems to be an anomaly in the world of selfdiffusion and exchange experiments. Polycrystalline iron, immersed in active FelCKhia and FelClChh, showed negligible penetration of tagged iron.…”
Section: / Journal Of Chemical Educationmentioning
confidence: 99%
“…Iron (12) Iron seems to be an anomaly in the world of selfdiffusion and exchange experiments. Polycrystalline iron, immersed in active FelCKhia and FelClChh, showed negligible penetration of tagged iron.…”
Section: / Journal Of Chemical Educationmentioning
confidence: 99%
“…'radiocolloid' formation [7], 3. ion exchange adsorption in a corrosion layer, usually of oxide [8], 4. exchange, where a metal dips into a Solution of its own ions [9], and 5. by electrica! double layer adsorption [10].…”
Section: Introductionmentioning
confidence: 99%