Quantum defect orbital calculation of oscillator strengths for electronic transitions in triatomic hydrogen

Martı́n, I.; Lavin, Anita; Karwowski, M.; Karwowski, Jacek

doi:10.1016/0009-2614(96)00367-3

Cited by 38 publications

(32 citation statements)

References 10 publications

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“…The decrease in the magnitude of k p that appears to take place below 70 km is a consequence of the increase in optical depth and the corresponding attenuation of the solar flux in that region, resulting in a decrease in the solar irradiance, according to Eq. (9). In opposition to this feature, the photolysis rate of CF 3 Cl at 127.95 nm is practically constant in all the analyzed altitude range.…”

Section: Photodissociation Rate Constants For Cf 2 CL 2 and Cf 3 Clmentioning

confidence: 57%

“…It may thus be expected that the attenuation suffered by this radiation will be almost negligible, and E Х E 0 , according to Eq. (9). It is then inferred that the dissociative photoionization of CF 2 Cl 2 is, most likely, the fastest fragmentation of the three processes considered in the studied altitude range.…”

Section: Photodissociation Rate Constants For Cf 2 CL 2 and Cf 3 Clmentioning

confidence: 97%

“…The MQDO technique, formulated to study molecular Rydberg transitions, has been described in detail elsewhere [8,9]. A brief summary of this method follows.…”

Section: Absorption Intensitiesmentioning

confidence: 99%

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Application of spectral intensities through a model potential approach to the prediction of photodissociation rate constants of CFC molecules in the ionosphere

Martı́n

Mayor

Velasco

2004

Int J of Quantum Chemistry

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Absorption of high-frequency radiation by chlorofluorocarbon (CFC) compounds in the ionosphere leads to their photoionization and photodissociation. Rydberg states are known to play an essential role in the initiation of photochemical processes. The photoabsorption intensities in both bound and continuous spectral regions, through all the allowed Rydberg channels, of two Freon molecules, have been first calculated. Then, through the use of the intensity data, photolysis rate constants corresponding to dissociation pathways in zones E and D of the ionosphere have been determined. An extension of the molecular quantum defect orbital approach has been used to supply these rate constants for the first time. Neither previous measurements nor theoretical calculations on these properties have, to our knowledge, been reported.

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Section: Photodissociation Rate Constants For Cf 2 CL 2 and Cf 3 Clmentioning

confidence: 57%

Section: Photodissociation Rate Constants For Cf 2 CL 2 and Cf 3 Clmentioning

confidence: 97%

See 1 more Smart Citation

Application of spectral intensities through a model potential approach to the prediction of photodissociation rate constants of CFC molecules in the ionosphere

Martı́n

Mayor

Velasco

2004

Int J of Quantum Chemistry

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“…In QDT frameworks, the Rydberg electron energy levels [16] are expressed in terms of the total quantum defect µ λ ≡ µ…”

Section: Ii2 Radial Functions and Bound State Energiesmentioning

confidence: 99%

“…In their earlier works (16,17 ) the authors of Ref. (15) noted the importance of correct account for angular dependence of the molecular wavefunctions.…”

Section: Introductionmentioning

confidence: 97%

Oscillator Strengths for Rydberg States in the Polar Molecule NeH

Alcheev¹,

Chernov²,

Zon³

2002

Journal of Molecular Spectroscopy

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Miniemulsion copolymerization of n‐butyl methacrylate with crosslinking monomers

Ghazaly

Daniels

Dimonie

et al. 2001

J of Applied Polymer Sci

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Miniemulsion copolymerization of n‐butyl methacrylate and crosslinking monomers such as a macromonomer crosslinker (Mac), ethylene glycol dimethacrylate (EGDMA), or an aliphatic urethane acrylate macromonomer (AUA) was utilized to obtain crosslinked latex particles. The crosslinking monomers were added at 0.2 mol %, on the basis of the amount of n‐butyl methacrylate utilized in a polymerization. The development of the gel content during the copolymerization reaction differs depending on the type of the crosslinking monomer. In addition to the crosslinking reactions between the n‐butyl methacrylate and the crosslinking monomers, other kinetic events, such as microphase separation, may have occurred, giving rise to different particle morphologies, dependent on the type of initiator used (i.e., oil‐soluble or water‐soluble). © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1721–1730, 2001

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Quantum defect orbital calculation of oscillator strengths for electronic transitions in triatomic hydrogen

Cited by 38 publications

References 10 publications

Application of spectral intensities through a model potential approach to the prediction of photodissociation rate constants of CFC molecules in the ionosphere

Application of spectral intensities through a model potential approach to the prediction of photodissociation rate constants of CFC molecules in the ionosphere

Oscillator Strengths for Rydberg States in the Polar Molecule NeH

Miniemulsion copolymerization of n‐butyl methacrylate with crosslinking monomers

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