Quantitative Analysis of Some C<sub>10</sub> Dibasic Acids and Associated Monobasic Acids by High Temperature Chromatography

Bartsch, Rüdiger; Miller, F. D.; Trent, F. M.

doi:10.1021/ac60165a015

Cited by 17 publications

(1 citation statement)

References 8 publications

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“…Adipic acid was determined as its methyl ester after addition of α-methyl-α-nitrosourea into the aliquot. [15] The TOF (turnover frequencies) values were determined from the initial rates of substrate consumption. After the reaction, water was added to the reaction mixture, the catalyst was separated by centrifugation, washed with water, dried in air, and checked by IR.…”

Section: Methodsmentioning

confidence: 99%

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation

et al. 2009

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8-(1) revealed a unique catalytic performance in the selective oxidation of organic compounds with aqueous hydrogen peroxide. The selectivity of alkene oxidation strongly depends on the amount of acidic protons in the cationic part of 1, which can be controlled by pH of precipitation of the TBA salt. Selectivities of almost 100 % were achieved for cyclohexene epoxidation by using TBA 5.5 Na 1.5 K 0.5 H 0.5 -1. In the presence of TBA 5.5 K 0.5 H 2 -1, cyclohexene epoxide readily transformed into trans-1,2-cyclohexanediol, 2-hydroxycyclohexanone, and C-C bond-cleavage products. No allylic oxidation products were found. Vicinal diols yielded α-hydroxyketones and (di)carboxylic acids. Ketonization of cyclohexanol proceeded with selectivity as high as 98 %, whereas 1-hexanol produced hexanal and hexanoic acid. The oxidation products are consistent with a heterolytic mechanism of H 2 O 2 activation. The stability of 1 under turnover condi-

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Section: Methodsmentioning

confidence: 99%

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation

et al. 2009

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Anwendung der Gas‐Chromatographie auf dem Fettgebiet I: Methodik und Schrifttum

Kaufmann

Mankel

Lehmann

1961

Fette, Seifen, Anstrichm.

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Anwendung der Gas‐Chromatographie auf dem Fettgebiet III: Einfluß der Herstellungsverfahren der Fettsäure‐methylester auf das quantitative Ergebnis

Kaufmann¹,

Mankel²

1963

Fette, Seifen, Anstrichm.

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Quantitative Analysis of Some C₁₀ Dibasic Acids and Associated Monobasic Acids by High Temperature Chromatography

Cited by 17 publications

References 8 publications

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation

Anwendung der Gas‐Chromatographie auf dem Fettgebiet I: Methodik und Schrifttum

Anwendung der Gas‐Chromatographie auf dem Fettgebiet III: Einfluß der Herstellungsverfahren der Fettsäure‐methylester auf das quantitative Ergebnis

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Quantitative Analysis of Some C10 Dibasic Acids and Associated Monobasic Acids by High Temperature Chromatography

Cited by 17 publications

References 8 publications

Unique Catalytic Performance of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8–: The Role of 5‐Coordinated Titanium in H2O2 Activation

Unique Catalytic Performance of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8–: The Role of 5‐Coordinated Titanium in H2O2 Activation

Anwendung der Gas‐Chromatographie auf dem Fettgebiet I: Methodik und Schrifttum

Anwendung der Gas‐Chromatographie auf dem Fettgebiet III: Einfluß der Herstellungsverfahren der Fettsäure‐methylester auf das quantitative Ergebnis

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Quantitative Analysis of Some C₁₀ Dibasic Acids and Associated Monobasic Acids by High Temperature Chromatography

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation

Unique Catalytic Performance of the Polyoxometalate [Ti₂(OH)₂As₂W₁₉O₆₇(H₂O)]^8–: The Role of 5‐Coordinated Titanium in H₂O₂ Activation