Numerous studies have attempted the oxygen evolution
reaction (OER),
a key half-reaction for water electrolysis, with low-cost catalysts
exhibiting high activity and durability. This study reports a novel
catalyst-design strategy for the heterogeneous growth of iron oxide
(Fe2O3) nanoparticles on surface-functionalized
multiwall carbon nanotubes (MWCNTs) through pulsed laser ablation
(PLA). Strong physicochemical interactions at the functional Fe2O3 nanoparticles/conductive MWCNT support interface
are confirmed by spectroscopic and computational investigations; the
functional interface promotes charge transfer kinetics and reduces
the energy barrier for the rate-determining step of OER. Furthermore,
semi-circularly arranged Fe2O3 nanoparticles
on the one-dimensional tubular MWCNT support, originating from heterogeneous
nucleation and growth during the PLA process, facilitate mass and
ion transfer during the OER. Thus, the optimized nanohybrid (0.5Fe@MWCNT)
exhibits a low overpotential (310 mV) to generate a current density
of 10 mA cm–2 and possesses excellent durability,
maintaining a stable current output during 10 h of continuous OER
in a 1.0 M KOH electrolyte. Moreover, this synthetic strategy is economically
advantageous, as it requires a total processing time of less than
1 h.