volume 60, issue 12, P4780-4789 1974
DOI: 10.1063/1.1680981
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Abstract: Expressions are derived for the transition moments and absorption resulting from the electric moment induced in one molecule of a pair by the field of the quadrupole moments of a neighbor with axial or near axial symmetry. Values of relevant matrix elements of squares and products of direction cosines are included. For axial polar molecules, the infrared absorption has a different frequency dependence than that by permanent dipoles, permitting separation of the effects. For asymmetric rotors with nearly axial…

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