2013
DOI: 10.1039/c2ce26431e
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Abstract: Preparation and crystal structures of the isomeric series 4-tolyl-1,2,3,5-dithiadiazolyl, (o-MeC 6 H 4 CNSSN) 2 , (m-MeC 6 H 4 CNSSN) 2 and (p-MeC 6 H 4 CNSSN) 2 3

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Cited by 18 publications
(27 citation statements)
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“…64,65 This interaction stabilizes the singlet ground state which is experimentally supported by χT values ~ 0 emu.K.mol -1 at low temperature. [26][27][28][29] Passmore was the first to indicate that the "closed-shell" dimerization of DTDA radicals inadequately described the electronic ground state of these materials and that they had some diradical character, 23 more recently studied computationally by Kertesz. 24 This behaviour has also been observed in other thiazyl radicals.…”
Section: Discussionmentioning
confidence: 99%
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“…64,65 This interaction stabilizes the singlet ground state which is experimentally supported by χT values ~ 0 emu.K.mol -1 at low temperature. [26][27][28][29] Passmore was the first to indicate that the "closed-shell" dimerization of DTDA radicals inadequately described the electronic ground state of these materials and that they had some diradical character, 23 more recently studied computationally by Kertesz. 24 This behaviour has also been observed in other thiazyl radicals.…”
Section: Discussionmentioning
confidence: 99%
“…The structural data for the previously reported Cl 2 C 6 H 3 CNSSN • derivatives [26][27][28] (DIXMII, DIXMOO, DIXNAB. DIXNEF, MEJZIL) reveals a weakening of the dimerization enthalpy as the intradimer S … S contacts increases.…”
Section: Discussionmentioning
confidence: 99%
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