A general formulation for surface chemical reactions is used with a nite element heat conduction code to compare computations of the ablated mass ux from carbon bodies experiencing conditions representative of Earth reentry. Several credible models for the surface chemical kinetics are exercised with the formulation and are compared both to each other and to test data obtained by the Passive Nosetip Technology program in the mid-1970s. Sublimation of C 5 and C 7 is shown to be a concern for surface temperatures greater than about 3900 K. The best match between measurements and the calculations is obtained with surface chemical models that use the usual CO formation reactions and the sublimation of C 1 -C 3 but that also include CN formation and the sublimation of C 5 and C 7 . For surface temperatures above 3500 K and for similar assumptions for the equilibrium vapor pressure and evaporation coef cients of the sublimated species, the net reaction rate approach and the surface site occupation approach give similar ablated mass uxes.
Nomenclatureenergy, J/kg F = Gibbs free energy, J/gmol F = radiation view factor f = kinetic rate factor, 1=m 2 s or nondimensional H 0 298 = enthalpy of formation at 298 K, J/gmol h = enthalpy, J/kg h = Planck's constant, J ¢ s k = Boltzmann's constant, J/molecule ¢ K k = reaction rate constant, 1=m 2 s L = number of surface species l = surface species index M = molecular weight, kg/kmol m = mass per molecule, kg P m = mass ux, kg/m 2 s N 0 = Avogadro's number, 1=kmol P = pressure, N/m 2 P 0 = reference pressure, atmosphere, 0.101325 MPa p = pressure, N/m 2 Q = number of surface reactions q = chemical species index P q = heat ux, J/m 2 s R = linear correlation coef cient R u = universal gas constant, J/kmol ¢ K or J/gmol ¢ K r = forward reaction rate, m 2 s S = surface kinetic factor, 1/m 2 s or nondimensional T = temperature, K W = number of gaseous species w = gaseous species index X = mole fraction of gaseous species 125. Senior Member AIAA.°= concentration,kmol/kg " = emissivity " = parameter in surface species reaction constant = stoichiometric coef cient of surface reactants µ = surface species population fractioņ = stoichiometric coef cient of surface products ¹ = stoichiometric coef cient of gaseous products º = stoichiometric coef cient of gaseous reactants ¾ = Stefan-Boltzmann constant, J/m 2 s ¢ K 4 8 = modi cation factor in heat transfer relation Subscripts a = activation ab = ablation abspec = ablated species blow = blowing cw = cold wall diff = diffusion emittradn = emitted radiation eq = equilibrium er = erosion f = forward f = formation condn = uid conduction HAL = heating augmentation level i = mass species index incradn = incident radiation k = element index m = reaction index p = pressure pyrgas = pyrolysis gas q = reaction index r = recovery ref = reference re radn = re ected radiation s = species index s,l = solid to liquid solcondn = solid conduction stag = stagnation T = temperature und = underside u = universal v = volume w = wall º = vibrational 508 Downloaded...