2018
DOI: 10.1134/s1023193518140045
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Predicting Microdistribution of Metal Electrodeposition Rate from Electrolytes with Positive and Negative Leveling Power

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“…The ability of the present additive-free electrolyte for surface levelling and the role of the coating thickness in relation to the scale of the surface damage may suggest that the observed levelling is a pure geometric effect. In case of geometric levelling, for which a uniform current distribution is assumed along the substrate surface [18], surface protrusions become gradually wider, while depressions in the surface become narrower with increasing coating thickness. In contrast, a non-uniform current distribution with larger current densities at local depressions than at protrusions is caused by a topography-dependent adsorption of levelling agents and results in true levelling [13].…”
Section: Resultsmentioning
confidence: 99%
“…The ability of the present additive-free electrolyte for surface levelling and the role of the coating thickness in relation to the scale of the surface damage may suggest that the observed levelling is a pure geometric effect. In case of geometric levelling, for which a uniform current distribution is assumed along the substrate surface [18], surface protrusions become gradually wider, while depressions in the surface become narrower with increasing coating thickness. In contrast, a non-uniform current distribution with larger current densities at local depressions than at protrusions is caused by a topography-dependent adsorption of levelling agents and results in true levelling [13].…”
Section: Resultsmentioning
confidence: 99%