“…Up to now, multitudinous semiconductors have been explored as photocatalysts for solar hydrogen generation, however, most of them have low photocatalytic performance because of the weak light absorption and inefficient photointroduced charge carriers separation/transport, which greatly hinder their practical and large-scale applications. [5][6][7][8] Two-dimensional (2D) photocatalysts have been proven to be promising to solve the above-mentioned problems due to their abundant surface-active sites, huge specific surface area, and excellent charge carrier separation. 4,6,[9][10][11][12][13][14] Very recently, ZnIn 2 S 4 (ZIS), especially single/few-layered 2D ZIS has been considered as an outstanding photocatalyst for hydrogen generation, mainly due to its good chemical stability, suitable band gap, and excellent photocatalytic performance.…”