2008
DOI: 10.1103/physreva.78.012503
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Potassium ground-state scattering parameters and Born-Oppenheimer potentials from molecular spectroscopy

Abstract: We present precision measurements with MHz uncertainty of the energy gap between asymptotic and well bound levels in the electronic ground state X 1 Σ + g of the 39 K2 molecule. The molecules are prepared in a highly collimated particle beam and are interrogated in a Λ-type excitation scheme of optical transitions to long range levels close to the asymptote of the ground state, using the electronically excited state A 1 Σ + u as intermediate one. The transition frequencies are measured either by comparison wit… Show more

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Cited by 74 publications
(97 citation statements)
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“…In the Born-Oppenheimer approximation, V (R) is independent of reduced mass, so the values of /π for different isotopologs are related by simple mass scaling. For alkali metals heavier than Li, such mass scaling is very accurate [28][29][30][54][55][56]. For Li, however, significant corrections are needed, as shown in Sec.…”
Section: A Born-oppenheimer Correctionsmentioning
confidence: 99%
See 1 more Smart Citation
“…In the Born-Oppenheimer approximation, V (R) is independent of reduced mass, so the values of /π for different isotopologs are related by simple mass scaling. For alkali metals heavier than Li, such mass scaling is very accurate [28][29][30][54][55][56]. For Li, however, significant corrections are needed, as shown in Sec.…”
Section: A Born-oppenheimer Correctionsmentioning
confidence: 99%
“…For heavy diatomic molecules, the differences between the binding energies for different isotopes can be well accounted for by retaining the same potential curves and simply changing the masses used in the calculation [28][29][30][31][32][33][34]. However, it is known that mass corrections due to the breakdown of the BornOppenheimer approximation are important for light species such as H 2 [35,36] and also have significant effects in LiK [37] and LiRb [38].…”
Section: Introductionmentioning
confidence: 99%
“…Finaly, we set the magnetic field B = 85 G, where interspecies scattering length a = −20 a 0 . At this magnetic field, the dual BEC is miscible because the interspecies scattering length is much smaller than the intra-species scattering length (a KK = 63.5(6) a 0 [31], a RbRb = 100.4(1) a 0 [32]). …”
Section: K Atoms Andmentioning
confidence: 99%
“…By contrast to 39 K, it varies only slightly from a background value of approximately +63 a 0 . Direct evaporation to Bose-Einstein condensation has been achieved in the magnetically trappable f = 2, m f = 2 excited state [44], where the scattering length is +61 a 0 [31]. Efficient evaporation is also expected for atoms in the f = 1, m f = 1 ground state confined in an optical dipole trap.…”
Section: Fig 4 (Color Online)mentioning
confidence: 99%