1997
DOI: 10.1002/(sici)1099-0488(19970715)35:9<1349::aid-polb5>3.0.co;2-h
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Polystyrene-glass bead composites: Maxwell-Wagner-sillars relaxations and percolation
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1997
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Cited by 32 publications
(33 citation statements)
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“…At the same time, dielectric losses increased rapidly from 10 kHz onward accompanied by steeper declining of relative permittivity, which is typical indication of a relaxation mechanism taking place (Figure ). However, the change of relative permittivity was quite small, around 7% from 100 Hz to 1 MHz, and it was at a similar level as that obtained at ∼10 GHz, suggesting that only minor level of dielectric relaxation phenomena is occurring due to Maxwell–Wagner–Sillars (MWS) type of the polarization . Such polarization takes place typically at acoustic frequencies and is associated with, for example, immobilized free charges on the interfaces of different media having contrast in conductivity and permittivity.…”
Section: Discussionmentioning
confidence: 51%
“…At the same time, dielectric losses increased rapidly from 10 kHz onward accompanied by steeper declining of relative permittivity, which is typical indication of a relaxation mechanism taking place (Figure ). However, the change of relative permittivity was quite small, around 7% from 100 Hz to 1 MHz, and it was at a similar level as that obtained at ∼10 GHz, suggesting that only minor level of dielectric relaxation phenomena is occurring due to Maxwell–Wagner–Sillars (MWS) type of the polarization . Such polarization takes place typically at acoustic frequencies and is associated with, for example, immobilized free charges on the interfaces of different media having contrast in conductivity and permittivity.…”
Section: Discussionmentioning
confidence: 51%
“…The effect of the diameter, the volume fraction and the surface coating of glass beads on the interfacial relaxation characteristics have been studied [34][35][36]. A very good agreement was found between experiments and calculations embedded in an insulating matrix [37].…”
Section: Introductionmentioning
confidence: 64%
“…The decrease in permittivity was partly due to the smaller amount (50 vol.% vs. 48 vol.%) of ceramic particles in the composite (permittivity difference 8-10 % using the commonly used Bruggemans model [16,18]). Also, the surfactant has a low permittivity whereas P(VDF-TrFE) is known to be a polymer with very high permittivity (Table 1), and about 2.5 vol.% of the P(VDF-TrFE) was replaced with surfactant in the present composition (compared to 48 vol.% composite without surface treatment) [12,35]. These two effects are evident from the compositional differences between the two composites.…”
Section: Resultsmentioning
confidence: 85%
