1996
DOI: 10.1002/(sici)1099-0488(19960915)34:12<2099::aid-polb15>3.0.co;2-x
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Polyradical distribution in free radical crosslinking of polymer chains
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1996
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Cited by 19 publications
(7 citation statements)
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“…However, it should be pointed out that the developments of weight-average chain length, as well as of the three second-order polymer moments in the pregel period, can be readily investigated using Eqs. (18-20) and (23). Higher order average chain lengths (z, z + 1, etc.)…”
Section: Resultsmentioning
confidence: 99%
“…However, it should be pointed out that the developments of weight-average chain length, as well as of the three second-order polymer moments in the pregel period, can be readily investigated using Eqs. (18-20) and (23). Higher order average chain lengths (z, z + 1, etc.)…”
Section: Resultsmentioning
confidence: 99%
“…[23,24] This approach presents some additional important advantages, such as the possibility of prediction of the distribution of molecular sizes (very difficult otherwise) or the analysis of reversible polymerization. Its main drawback lies in the computational resources needed for a reasonable accuracy.…”
Section: Discussionmentioning
confidence: 99%
“…This result simply confirms previous statements about the existence of polyradicals, which is known to be important in the vicinity of gelation. [50,51] As we are considering an ideal CSTR, the outflow composition is the same inside the reactor. Neglecting radical outflow, in spite of its low concentration, is obviously an approximation with an effect becoming more pronounced as the space-time becomes smaller.…”
Section: When a New Methods For Simulation Is Presented The Natural Qumentioning
confidence: 99%
