Polypyrrole Nanoparticles Doped with Fullerene Uniformly Distributed in the Polymeric Phase: Synthesis, Morphology, and Electrochemical Properties

Wysocka‐Żołopa, Monika; Goclon, Jakub; Basa, Anna; Winkler, Krzysztof

doi:10.1021/acs.jpcc.8b07681

Cited by 19 publications

(11 citation statements)

References 124 publications

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“…Various methods have been applied to produce these types of materials, such as i) solid-state blending, [70,71] ii) drop coating, [72][73][74][75][76][77][78] iii) chemical and electrochemical polymerization. [30,70,[79][80][81][82][83][84] The most frequently used method to prepare polymer and fullerene composites is the solid state blending of both components.…”

Section: Formation and Structurementioning

confidence: 99%

Section: +mentioning

confidence: 99%

“…Various methods have been applied to produce these types of materials, such as i) solid‐state blending, [ 70,71 ] ii) drop coating, [ 72–78 ] iii) chemical and electrochemical polymerization. [ 30,70,79–84 ]…”

Section: Fullerene Incorporated Into Conducting Polymeric Networkmentioning

confidence: 99%

“…A C 60 @polypyrrole composite material was obtained using this method. [ 30 ] Fullerene is unable to directly oxidize pyrrole and initiate the polymerization process. However, it slowly oxidizes pyrrole oligomers present in the solution.…”

Section: Fullerene Incorporated Into Conducting Polymeric Networkmentioning

confidence: 99%

“…The simplest and most common structures are composites formed from the polymeric chains and fullerenes. Fullerenes form a crystalline phase in the polymeric matrix [ 30 ] or are incorporated as guest molecules into polymeric chain containing host moieties. [ 31 ] In both cases, covalent interactions are not formed between fullerenes and the polymeric network.…”

Section: Introductionmentioning

confidence: 99%

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Fullerene‐Based Conducting Polymers:n‐Dopable Materials for Charge Storage Application

Grądzka

Wysocka‐Żołopa

Winkler

2020

Advanced Energy Materials

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structure, which can be easily covalently modified. Progress in extensive organic chemistry of fullerene development facilitates the production of a variety of fullerene derivatives with different structures and physicochemical properties. Additionally, the polyhedral structure of fullerenes containing a large number of bonding sites provides an opportunity for a wide range of covalent modifications. Polymeric structures containing fullerene moieties represent a particularly large class of materials in terms of their number, composition, structure, morphology, and physicochemical properties. [24-29] Some of the most common structures of these polymeric materials are schematically shown in Figure 1. The simplest and most common structures are composites formed from the polymeric chains and fullerenes. Fullerenes form a crystalline phase in the polymeric matrix [30] or are incorporated as guest molecules into polymeric chain containing host moieties. [31] In both cases, covalent interactions are not formed between fullerenes and the polymeric network. However, van der Waals and electrostatic interactions, as well as possible charge transfer between both components of the composite significantly modulate the electronic structure of the polymer/fullerene interphase. [32,33] A stronger electronic interaction between the polymer component and fullerene moieties is expected for the system in which carbon cages are covalently bound to the polymeric chain or covalently incorporated into the polymeric backbone. In the case of in-chain structures, fullerene moieties are separated by short organic conjugated linkers, [34-37] small inorganic linkers, [37-39] or metal atoms and metal complexes. [7,8,29,40-42] A large group of fullerene-based materials consists of organic conducting polymers containing fullerenes attached covalently to the polymer chain by the linker. [43-46] The physicochemical properties of these materials depend on the polymer chain, linker structures, and the density of fullerene moieties within the polymeric material. Similar to olefins, fullerene form homopolymers through [2+2] cycloaddition. [47-51] Fullerene homopolymers, in-chain and side chain fullerene polymers can be cross-linked to form 3D polymeric structures. A large number of reactive π-bond centers in the fullerene moiety enable the formation of star-shaped macromolecular systems with polymeric chains covalently grafted to the C 60. [52-57] In common structures, the number of linked This article provides a comprehensive review of research related to the formation and electrochemical properties of fullerene-based conducting polymeric materials. The paper begins with an overview of composites containing fullerenes incorporated into the network of a conducting polymer through van der Walls, electrostatic, or guest-host interactions. The properties of these composites are generally a superposition of the properties of the individual components. More attention is devoted to the structures in which fullerene is covalently incorporated into the polyme...

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Section: Formation and Structurementioning

confidence: 99%

Section: +mentioning

confidence: 99%

Section: Fullerene Incorporated Into Conducting Polymeric Networkmentioning

confidence: 99%

Section: Fullerene Incorporated Into Conducting Polymeric Networkmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Fullerene‐Based Conducting Polymers:n‐Dopable Materials for Charge Storage Application

Grądzka

Wysocka‐Żołopa

Winkler

2020

Advanced Energy Materials

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Fullerene‐Intercalated Graphitic Carbon Nitride as a High‐Performance Anode Material for Sodium‐Ion Batteries

Shen

et al. 2021

Energy & Environ Materials

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Two‐dimensional (2D) graphitic carbon nitride (g‐CN) is a promising anode material for sodium‐ion batteries (SIBs), but its insufficient interlayer spacing and poor electronic conductivity impede its sodium storage capacity and cycling stability. Herein, we report the fabrication of a fullerene (C60)‐modified graphitic carbon nitride (C60@CN) material which as an anode material for SIBs shows a high‐reversible capacity (430.5 mA h g−1 at 0.05 A g−1, about 3 times higher than that of pristine g‐CN), excellent rate capability (226.6 mA h g−1 at 1 A g−1) and ultra‐long cycle life (101.2 mA h g−1 after 5000 cycles at 5 A g−1). Even at a high‐active mass loading of 3.7 mg cm−2, a reversible capacity of 316.3 mA h g−1 can be obtained after 100 cycles. Such outstanding performance of C60@CN is attributed to the C60 molecules distributed in the g‐CN nanosheets, which enhance the electronic conductivity and prevent g‐CN sheets from restacking, thus resulting in enlarged interlayer spacing and exposed edge N defects (pyridinic N and pyrrolic N) for sodium‐ion storage. Furthermore, a sodium‐ion full cell combining C60@CN anode and NVPF@rGO cathode provides high‐coulombic efficiency (>96.5%), exceptionally high‐energy density (359.8 W h kganode−1 at power density of 105.1 W kganode−1) and excellent cycling stability (89.2% capacity retention over 500 cycles at 1 A ganode−1). This work brings new insights into the field of carbon‐based anode materials for SIBs.

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Electrochemical synthesis of polypyrrole composite with modified gold nanoparticles for electrochemical detection of ascorbic acid, dopamine and acetaminophen in different pharmaceutical samples

Amiri,

Golmohammadi,

Safari

et al. 2024

Polym. Bull.

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Polypyrrole Nanoparticles Doped with Fullerene Uniformly Distributed in the Polymeric Phase: Synthesis, Morphology, and Electrochemical Properties

Cited by 19 publications

References 124 publications

Fullerene‐Based Conducting Polymers:n‐Dopable Materials for Charge Storage Application

Fullerene‐Based Conducting Polymers:n‐Dopable Materials for Charge Storage Application

Fullerene‐Intercalated Graphitic Carbon Nitride as a High‐Performance Anode Material for Sodium‐Ion Batteries

Electrochemical synthesis of polypyrrole composite with modified gold nanoparticles for electrochemical detection of ascorbic acid, dopamine and acetaminophen in different pharmaceutical samples

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