2015
DOI: 10.1007/s00289-015-1498-x
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Abstract: Ring-opening polymerizations of four kinds of monomers such as glycidyl phenyl ether, oxetane (OX), e-caprolactone (CL), and 2,2-dimethyltrimethylene carbonate were performed with a silica-supported catalyst based on heteropolyacid ammonium salt, (NH 4 ) 3 PW 12 O 40 /SiO 2 . Preparation of the catalyst was done by an impregnation of (NH 4 ) 3 PW 12 O 40 onto SiO 2 in aqueous ammonia, followed by its calcination. Selectivities for skeletal isomerizations of 1-butene exhibited a strong acidity of the (NH 4 ) 3 … Show more

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