Poly(?-caprolactone-b-glycolide) and poly(D,L-lactide-b-glycolide) diblock copolyesters: Controlled synthesis, characterization, and colloidal dispersions

Versatile Copolymerization of Glycolide and rac-Lactide by Dimethyl(salicylaldiminato)aluminum Compounds

“…The opposite sequence of monomers addition led mainly to poly(glycolide) and a low amount of the block copolymer. The importance of the order of the monomer addition in the block copolymerization was previously underlined in the literature. , …”

Versatile Copolymerization of Glycolide and rac-Lactide by Dimethyl(salicylaldiminato)aluminum Compounds

“…The opposite sequence of monomers addition led mainly to poly(glycolide) and a low amount of the block copolymer. The importance of the order of the monomer addition in the block copolymerization was previously underlined in the literature. , …”

High- T g PLA copolymers via base-catalyzed transesterification of PLA with 2,5,7-trioxabicyclo[2.2.2]octan-6-one

“…Copolymerization of LA with glycolide, 65 δ-valerolactone, 66 β-butyrolactone, 67,68 ε-caprolactone 69–73 and 1.5-dioxoheptane-2-one 74–76 has been extensively investigated with different catalysts. Random, gradient, or block copolymers have been prepared, but the T g s of all the random copolymers are lower than that of PLA.…”

Design and Synthesis of Different Types of Poly(Lactic Acid)

“…Block copolymers of lactide with glycolide have been prepared by sequential addition of monomer onto the reactive chain end of polymer produced from another monomer, or by using a hydroxyl-terminated homopolymer as a chain transfer agent [17].…”

Versatile Copolymerization of Glycolide and rac-Lactide by Dimethyl(salicylaldiminato)aluminum Compounds

“…The opposite sequence of monomers addition led mainly to poly(glycolide) and a low amount of the block copolymer. The importance of the order of the monomer addition in the block copolymerization was previously underlined in the literature. , …”

High- T g PLA copolymers via base-catalyzed transesterification of PLA with 2,5,7-trioxabicyclo[2.2.2]octan-6-one

“…Copolymerization of LA with glycolide, 65 δ-valerolactone, 66 β-butyrolactone, 67,68 ε-caprolactone 69–73 and 1.5-dioxoheptane-2-one 74–76 has been extensively investigated with different catalysts. Random, gradient, or block copolymers have been prepared, but the T g s of all the random copolymers are lower than that of PLA.…”

Design and Synthesis of Different Types of Poly(Lactic Acid)

“…Block copolymers of lactide with glycolide have been prepared by sequential addition of monomer onto the reactive chain end of polymer produced from another monomer, or by using a hydroxyl-terminated homopolymer as a chain transfer agent [17].…”

Versatile Copolymerization of Glycolide and rac-Lactide by Dimethyl(salicylaldiminato)aluminum Compounds

“…The opposite sequence of monomers addition led mainly to poly(glycolide) and a low amount of the block copolymer. The importance of the order of the monomer addition in the block copolymerization was previously underlined in the literature. , …”

High- T g PLA copolymers via base-catalyzed transesterification of PLA with 2,5,7-trioxabicyclo[2.2.2]octan-6-one

“…Copolymerization of LA with glycolide, 65 δ-valerolactone, 66 β-butyrolactone, 67,68 ε-caprolactone 69–73 and 1.5-dioxoheptane-2-one 74–76 has been extensively investigated with different catalysts. Random, gradient, or block copolymers have been prepared, but the T g s of all the random copolymers are lower than that of PLA.…”

Design and Synthesis of Different Types of Poly(Lactic Acid)

“…Block copolymers of lactide with glycolide have been prepared by sequential addition of monomer onto the reactive chain end of polymer produced from another monomer, or by using a hydroxyl-terminated homopolymer as a chain transfer agent [17].…”