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Cited by 14 publications
(2 citation statements)
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References 4 publications
(9 reference statements)
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“…The proposed mechanism involves an intermediate with three molecules of water present in the chromium octahedron: This mechanism explains not only the trans-cis isomerization of Cr(C204) 2(H20) 2 -but also the exchange of H20 for Cl in the CrCl2(H20)4ion, as evidenced by the almost identical 5* value of -16.3 e.u. for the latter reaction (188). A reasonable assumption is that kt and k¡ » fci » k4, which is consistent with the high negative entropy of activation (184).…”
Section: Reactions and Reaction Kineticssupporting
confidence: 54%
“…The proposed mechanism involves an intermediate with three molecules of water present in the chromium octahedron: This mechanism explains not only the trans-cis isomerization of Cr(C204) 2(H20) 2 -but also the exchange of H20 for Cl in the CrCl2(H20)4ion, as evidenced by the almost identical 5* value of -16.3 e.u. for the latter reaction (188). A reasonable assumption is that kt and k¡ » fci » k4, which is consistent with the high negative entropy of activation (184).…”
Section: Reactions and Reaction Kineticssupporting
confidence: 54%
“…There are also reports suggesting that chromium chloride has potential as an anti-depressant and alternatively to reduce lipid deposits [10,11]. [4,[18][19][20][21][22][23][24]. Therefore there may be significant speciation of chromium(III) in a physiological environment and it is not clear which of these species may have an impact on physiological processes in the body.…”
Section: Introductionmentioning
confidence: 99%