1982
DOI: 10.1021/ja00388a104
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Abstract: Anders als bei der Bindung von (Z,Z)‐ Bilirubin IXa an tierischen Serum‐Albumin (SA) weist die an menschliches SA gebundene Titelverbindung bei ihrer Photoisomerisierung nur eines der beiden möglichen Diastereomeren auf.

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Cited by 126 publications
(66 citation statements)
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“…The second fastest photoehemical reaction of bilirubin is structural isomerization to lumirubin (6). During phototherapy the serum concentration of lumirubin is lower than the concentration of the configurational isomers: 2 to 6 versus 15 to 20% of the total serum bilirubin.…”
Section: Discussionmentioning
confidence: 99%
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“…The second fastest photoehemical reaction of bilirubin is structural isomerization to lumirubin (6). During phototherapy the serum concentration of lumirubin is lower than the concentration of the configurational isomers: 2 to 6 versus 15 to 20% of the total serum bilirubin.…”
Section: Discussionmentioning
confidence: 99%
“…However, serial sampling at 15-20 min intervals for 180 min from 14 individual fetuses (91-139 days) showed that TSH was secreted in a markedly exaggerated pulsatile manner compared to that observed after birth. The mean amplitude of TSH pulses fell (p < 0.005) from 5.9 2 8.1 pU/ml in the fetuses to 2.1 + 1.1 pU/ml in five neonatal lambs (6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22) days) and to 1.5 f 0.4 pU/ml in three adult nonpregnant ewes. The mean pulse frequency for the 14 fetuses was 0.7 + 0.3 pulses/h and was reduced (p < 0.001) to 0.3 + 0.1 pulseslh in lambs and to 0.3 f 0.1 pulses/h in the ewes.…”
mentioning
confidence: 94%
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“…Photooxidation may also occur (5,6). Due to increased polarity, these isomers can be excreted in bile and urine, bypassing the need for conjugation.…”
mentioning
confidence: 99%
“…Other bilirubin isomers, including bilirubin-III α and bilirubin-XIII α, were eliminated because their 1 H NMR spectra are substantially different (McDonagh et al, 1982).…”
Section: Proposed Researchmentioning
confidence: 99%