Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers

Wang, Jifu; Yuan, Liang; Wang, Zhongkai; Rahman, Anisur; Huang, Yucheng; Zhu, Tianyu; Wang, Ruibo; Cheng, Jianjun; Wang, Chunpeng; Chu, Fuxiang; Tang, Chuanbing

doi:10.1021/acs.macromol.6b01997

Cited by 67 publications

(52 citation statements)

References 59 publications

(83 reference statements)

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“…It can be prepared from dehydroabietyl chloride and hydroxyethyl methacrylate according to Scheme 11, prior to neutralization, drying, evaporation and chromatography [146]. It can be widely used as a monomer in preparation of graft and block copolymers [146,166,167,168,169,170]. It is worth noting, that a similar compound dehydroabietic ethyl acrylate is a yellow, viscous liquid, which can be prepared from hydroxyethyl acrylate and dehydroabietyl chloride prior to filtration, precipitation and vacuum distillation [171].…”

Section: Rosin-based Chemicalsmentioning

confidence: 99%

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

et al. 2019

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A comprehensive review of the publications about rosin-based chemicals has been compiled. Rosin, or colophony, is a natural, abundant, cheap and non-toxic raw material which can be easily modified to obtain numerous useful products, which makes it an excellent subject of innovative research, attracting growing interest in recent years. The last extensive review in this research area was published in 2008, so the current article contains the most promising, repeatable achievements in synthesis of rosin-derived chemicals, published in scientific literature from 2008 to 2018. The first part of the review includes low/medium molecule weight compounds: Especially intermediates, resins, monomers, curing agents, surfactants, medications and biocides. The second part is about macromolecules: mainly elastomers, polymers for biomedical applications, coatings, adhesives, surfactants, sorbents, organosilicons and polysaccharides. In conclusion, a critical evaluation of the publications in terms of data completeness has been carried out with an indication of the most promising directions of rosin-based chemicals development.

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Section: Rosin-based Chemicalsmentioning

confidence: 99%

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

et al. 2019

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“…110–112 However, O-ATRP has also been adapted in batch systems to produce star polymers, 113 hyperbranched polymers, 114 surface-grafted polymers, 115 and application of bio-based monomers for homopolymer synthesis. 116…”

Section: Reversible Deactivation Crps In Flowmentioning

confidence: 99%

Photoinduced Controlled Radical Polymerizations Performed in Flow: Methods, Products, and Opportunities

Buss

Miyake

2018

Chem. Mater.

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Photoinduced controlled radical polymerizations (CRPs) have provided a variety of approaches for the synthesis of polymers possessing targeted structures, compositions, and functionalities with the added capability for spatial and temporal control, presenting the potential for new materials development. However, the scalability and reliability of these systems can be limited as a consequence of dependence on uniform irradiation of the reaction to produce well-defined products. In this perspective, we highlight the utility and promise of photo-CRP approaches through an overview of the adaptation of these methodologies to photo-flow reactor systems. Special emphasis is placed on the current state-of-the-art in polymerization scalability, reactor design, and polymer scope.

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“…Furfuryl methacrylate (FMA) is a monomer derived from a biomass feedstock, furfural, and a promising monomer due to its potential availability from different carbohydrates, inulin, and agricultural or forestry waste . FMA can be synthesized from methacrylic acid of bio‐origin from the oil of roman chamomile plant.…”

Section: Introductionmentioning

confidence: 99%

Sustainable self‐healing elastomers with thermoreversible network derived from biomass via emulsion polymerization

Sahu

Bhowmick

2019

J. Polym. Sci. Part A: Polym. Chem.

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Motivated by the growing demand for greener and sustainable polymer systems, self‐healing elastomers were prepared by emulsion polymerization of terpene and furfural‐based monomers. Both the method and the monomers were green and sustainable. The synthesized copolymers showed molecular weights between 59,080 and 84,210 Da and glass‐transition temperature (Tg) between −25 and −40 °C, implying rubbery properties. A set of one‐dimensional (1D) and two‐dimensional (2D) NMR spectroscopy supported the formation of the copolymer and nuclear spin–spin coupling in the copolymer. Reactivity ratios were determined by conventional linear method. A thermoreversible network was achieved for the first time by reacting the furan‐based polymer with bismaleimide (BM) as a crosslinker, via a Diels−Alder (DA) coupling reaction. The reversible nature of the polymer network was evidenced from infrared and NMR spectroscopy. The thermoreversible character of the DA crosslinked adduct was confirmed by applying retro‐DA reaction (observed in differential scanning calorimeter [DSC] analysis) and mechanical recovery was verified by repeated heating and cooling cycles. The network polymers displayed excellent self‐healing ability, triggered by heating at 130 °C for 4–12 h, when their scratched surface was screened by microscopic visualization. The healing efficiency of the crosslinked DA‐adduct was calculated as 78%, using atomic force microscopy. This work provides a green and efficient approach to prepare new green and functional materials. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 738–751

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Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers

Cited by 67 publications

References 59 publications

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

Advances in Rosin-Based Chemicals: The Latest Recipes, Applications and Future Trends

Photoinduced Controlled Radical Polymerizations Performed in Flow: Methods, Products, and Opportunities

Sustainable self‐healing elastomers with thermoreversible network derived from biomass via emulsion polymerization

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