Abstract:Herein, direct unactivated
C-N borylation of aromatic amines by a photocatalyst was achieved under mild
and metal-free conditions. The C-N borylation of aromatic amines with
bis(pinacolato)diboron (B<sub>2</sub>pin<sub>2</sub>) proceeded in the presence
of a pyrene catalyst under light irradiation (λ = 365 nm) <a>to afford desired borylated
products</a> and aminoborane as a byproduct. The yield of borylated product improved under a
CO<sub>2</sub> atmosphere. Reac… Show more
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