Photoelectron spectra and electronic structure of Zn(II)bis-β-diketonates with aromatic substituents by the PES, DFT, and OVGF methods

Vovna, V. I.; Chekh, Alexander S.; Korochentsev, V. V.; Tikhonov, Sergey A.; Samoilov, Ilya S.

doi:10.1016/j.molstruc.2020.128815

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2022

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“…A large number of special ligands have been synthesized for sensitizing the luminescence of metals [10][11][12][13][14][15][16][17], in particular, europium [18][19][20]. Among them βdiketones are excellent chelating ligands used to sensitize the luminescence of the europium ion and have proven themselves well [10,21,22]. For example, a study was presented to research the influence of structural effects on the photophysical properties of mono-βdiketonate and bis-β-diketonate complexes of Eu (III).…”

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confidence: 99%

Luminescent Coatings Based on (3-Aminopropyl)triethoxysilane and Europium Complex β-Diketophosphazene

et al. 2022

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The reaction of β-diketophosphazene with the europium (III) salt synthesized the corresponding metal complex which was structured with (3-aminopropyl)triethoxysilane and treated with dibenzoylmethane for additional coordination of europium atoms. The polymer thus obtained exhibits luminescence with a maximum of 615 nm, which is characteristic of europium. The polymer is thermally stable up to 300 °C, the coating based on it has a contact angle of 101°, and the adhesive strength of the coating to non-finished glass (according to ISO 2409: 2013) is 1 point.

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