Abstract:Selective partial C-Cl bond reduction represents an important strategy for the construction of valuable chloride-containing skeletons. Herein, we report an efficient and straightforward (deutero)hydrodechlorination strategy of trichloromethyl groups for the...
Recent years have witnessed the emergence of direct intermolecular C(sp3)–H bond functionalization using in situ generated aryl/alkyl radicals as a unique class of hydrogen atom transfer (HAT) agents.
Recent years have witnessed the emergence of direct intermolecular C(sp3)–H bond functionalization using in situ generated aryl/alkyl radicals as a unique class of hydrogen atom transfer (HAT) agents.
We report herein a visible-light induced, Fe-catalyzed selenocyclization of 2-ethynylanilines with diselenides under ambient conditions, employing ethyl acetate as a benign solvent with no stoichiometric additive required. The simple iron...
A novel strategy for the construction of polysubstituted pyrroles has been developed through the visible-light-induced single-electron reduction of CAr–I bonds and the following 1,5-hydrogen atom transfer (HAT) process.
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