volume 78, issue 1, P31-44 2006
DOI: 10.1590/s0001-37652006000100005
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Abstract: ABSTRACTBoth the regio-and stereo-chemistries of the photoreactions of 1-naphthyl (R)-2-phenylpropanoate have been investigated in poly(vinyl acetate) films in their glassy (at 5 • C) and melted (at 50 • C) states and in ethyl acetate. These results are compared with those from irradiations in polyethylene films and in n-hexane. The regioselectivity of the intermediate 1-naphthoxy/(R)-2-phenylpropanoyl radical pair combinations is much higher in both the melt and glassy states of poly(vinyl acetate) films tha…

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