Phenomenological manifestations of quantummechanical tunneling. III. Effect on relative tritiumdeuterium kinetic isotope effects J. Chem. Phys. 60, 2815 (1974); 10.1063/1.1681449Phenomenological manifestations of quantummechanical tunneling. II. Effect on Arrhenius preexponential factors for primary hydrogen kinetic isotope effectsThe extent of nonlinearity that quantum-mechanical tunneling, through one-dimensional Eckart barriers, can produce in Arrhenius plots is calculated as a function of barrier height (…
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