“…The inclusion of thin layers of absorbing materials, such as metals or semiconductors, into multilayer stacks, allows for the design of structures with significant absorption (and, by Kirchhoff's law, significant emittance) [21]. In recent years, this approach has been the subject of increased interest as an easy-to-fabricate alternative to metasurfaces for tailorable selective surface absorbance/reflectance [22,23,24,25,26,27], for the fabrication of hyperbolic metamaterials at optical frequencies comprising a TiN/(Al,Sc)N stack [28,29] or for the modification of thermal transport through the alteration of phononic wave propagation [30,31]. An investigation of the long-term stability of a TiN/(Al,Sc)N stacks under thermal annealing is presented in [32], where the stability of the structure turns out to be limited by the presence of Scandium, which has a high diffusivity at elevated temperatures.…”