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Cited by 80 publications
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References 15 publications
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“…However, during the course of this work, a number of relevant papers have appeared, and have been summarized in ref. (12); their conclusions confirm and amplify our own findings. A summary of this work has already appeared.12 EXPERIMENTAL…”
supporting
confidence: 88%
“…However, during the course of this work, a number of relevant papers have appeared, and have been summarized in ref. (12); their conclusions confirm and amplify our own findings. A summary of this work has already appeared.12 EXPERIMENTAL…”
supporting
confidence: 88%
“…This is similar to the study of Mei et al comparing Pd and PdAg for acetylene hydrogenation. 60 Therefore, while the alkene binding strength may be an important parameter in determining the selectivity, and may be responsible for the higher selectivity of Pd as compared to some other metals, 62 it does not explain the difference between Pd and PdAu. Instead, our DFT calculations indicate that the branching ratio between alkane formation and the formation of the terminal methyl group is the controlling factor.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…Hydrogen interacts with metal surfaces in many varied and important technological applications. This occurs in catalysis [1,2], as well as hydrogen separation [3,4], storage [5], and sensors [6]. The ability of the small atom to permeate metals and change their properties gives hydrogen–metal systems added significance; for instance, embrittlement of metals remains an obstacle to the transport and storage of hydrogen [7,8].…”
Section: Introductionmentioning
confidence: 99%