There
is a constant drive to develop ultra-high-performance multifunctional
coatings for existing construction used in modern engineering technologies.
For these materials to be used in unsound infrastructure protections,
they are required to present enhanced robustness while bearing functionalities
to meet multiple uses. Single-function coating is not smart enough
to provide satisfactory protection, and the preparation process of
multifunctional materials is complex, costly, and provides poor durability.
Thus, existing coatings are not suitable to generate an intelligent
closed-loop protection system. Herein, we report an innovative 5S
multifunctional intelligent coating (5SC) for existing construction
materials with superdurable, superhydrophobic, self-monitoring, self-heating,
and self-healing properties. The 5SC material showed highly durable
superhydrophobic properties as revealed by the main failure tests
of building materials including physical friction (abrasion, scratching),
100% tensile strain, photoaging (3000 h of ultraviolet (UV) aging),
acid corrosion (concentrated hydrochloric acid and sulfuric acid),
and freeze–thaw aging (salty solution). The coated surface
was highly sensitive to pressure, with monitoring thresholds from
1 to 30 000 N per 0.01 m2. It showed an early heating
rate as high as 6 °C/min while maintaining very good self-monitoring
and ice-melting drainage performance to protect the existing structures.
This novel composite material is suitable for constructions in extreme
areas where corrosion and freeze–thaw damage can occur. This
multifunctional material presents a very broad range of applications
and development potential in the construction field.