Panchromatic porphyrin-based dye-sensitized solar cells: from cosensitization to concerted companion dye approaches

Li, Zhemin; Li, Qizhao; Li, Chengjie; Xie, Yongshu

doi:10.1039/d3qm00770g

Cited by 2 publications

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“…On the basis of the calculated J sc and V oc , the J – V curves and the fill factor (FF) of three dyes can be predicted by using the following formulae: − .25ex2ex V = italickT q ln ⁡ J SC − J J S .25ex2ex J normalS = J SC exp true( q V OC kT true) − 1 .25ex2ex FF = J max V max J SC V OC where V denotes the photovoltage, J denotes the current, J S represents the reverse saturation current, J max is the maximum current density, and V max is the maximum photovoltage. The simulated J – V curves are illustrated in Figure , and according to this figure, the FF values of ZL003 , HX-1 , and HX-2 can be calculated as 0.89, 0.88, and 0.89, respectively (Table ).…”

Section: Resultsmentioning

confidence: 99%

Molecular Engineering Strategies of Spectral Matching and Structure Optimization for Efficient Metal-Free Organic Dyes in Dye-Sensitized Solar Cells: A Theoretical Study

Zheng,

Huang,

Liu

et al. 2024

J. Phys. Chem. A

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Metal-free organic dyes are promising dyes that can be applied widely in dye-sensitized solar cells (DSSCs). The rational design and selection of dyes with complementary absorption can promote the development of methods that can enhance the utilization of incident light by DSSCs, such as cosensitization and tandem devices. Based on these opinions, the structure of the reported high-performance metal-free organic dye ZL003 is used as a template to design two new metal-free organic dyes, HX-1 and HX-2, by replacing its donor unit with a 2-phenothiazine-phenylamine unit and fusing its three independent π-bridge units into a whole with the aim of driving the red shift and the blue shift of the absorption spectra of ZL003, respectively. Through theoretical investigation, it is demonstrated that the perfect complementary optical absorption of HX-1 and HX-2 can be realized as the shift of the absorption spectra of ZL003 to different directions, which means their feasibility to the application in cosensitization or tandem dye-sensitized solar cells (T-DSSCs). Furthermore, it is hypothesized that HX-1 may be the dye with better photovoltaic performance than ZL003 by modeling their intramolecular chargetransfer (ICT) processes, TiO 2 surface adsorption, and photovoltaic parameters. The short-circuit current density (J sc ) and photoelectric conversion efficiency (PCE) of HX-1 are 23.10 mA•cm −2 and 21.26% in theory, compared to those of 20.68 mA•cm −2 and 19.64% in ZL003 at the same computational level, respectively. In view of the complementary optical properties, the combination of HX-1 with HX-2 may be a reasonable option for dyes for the development of a highly efficient cosensitization system or T-DSSCs in the future. In terms of such findings, these two novel metal-free organic dyes may have bright prospects in the research of highly efficient DSSCs, and this work can provide a reference for the design of dyes with complementary absorption through simple structural adjustments of the realistic dyes with high photovoltaic performance.

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Section: Resultsmentioning

confidence: 99%

Molecular Engineering Strategies of Spectral Matching and Structure Optimization for Efficient Metal-Free Organic Dyes in Dye-Sensitized Solar Cells: A Theoretical Study

Zheng,

Huang,

Liu

et al. 2024

J. Phys. Chem. A

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“…88,93 Hence, the usage of coadsorbents requires elaborate design and careful optimization of the adsorption processes. 103,104…”

Section: Optimization Of Porphyrin Dye Based Dsscsmentioning

confidence: 99%

Recent advances in the approaches for improving the photovoltaic performance of porphyrin-based DSSCs

Huang,

Li,

et al. 2024

Chem. Commun.

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Panchromatic porphyrin-based dye-sensitized solar cells: from cosensitization to concerted companion dye approaches

Abstract: With the advantages of environmental friendliness, easy fabrication, and rich colors, dye-sensitized solor cells (DSSCs) are promising for applications in architectural decoration as well as power supply for low energy...

Cited by 2 publications

References 137 publications

Molecular Engineering Strategies of Spectral Matching and Structure Optimization for Efficient Metal-Free Organic Dyes in Dye-Sensitized Solar Cells: A Theoretical Study

Molecular Engineering Strategies of Spectral Matching and Structure Optimization for Efficient Metal-Free Organic Dyes in Dye-Sensitized Solar Cells: A Theoretical Study

Recent advances in the approaches for improving the photovoltaic performance of porphyrin-based DSSCs

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