Painting method for hydroxyapatite coating on titanium substrate

Abstract

Coating on prostheses and implantable devices is one of the ways to increase the osseointegration of these products. However, plasma spray techniques, that are normally used, present high complexity and high cost. In this work, a new methodology for coating with nanometric hydroxyapatite is presented, with a low cost and ease of production. The technique proposed involves the formation of a suspension of hydroxyapatite (HAp) and oil of turpentine (OT) and its application, with a paintbrush, on the titanium substrate. In order to qualify the process for medical devices, the properties of the titanium substrate, before and after the coating process, the calcium phosphate phases present and the adhesive bond of the coating were evaluated. The results indicated that thermal treatment does not affect the properties of ASTM F67 titanium in order to compromise the properties and the analyses, by X-ray diffraction and Raman spectroscopy, proved that no formation of second phases of calcium phosphate occurred. The adhesive bond assay showed that the coating behaved according to ISO 13779-2, i.e., it had adhesive bond values higher than 15 MPa. The proposed new coating method proved promising for the titanium coating and is an alternative to the complex and high cost processes normally used in metal implants.

Hydroxyapatite coating processes with EPD method and investigation of mechanical properties of coatings

“…Different methods are used for HA coating processes on metal implants. These; electrophoretic deposition (EPD), electrochemical deposition, thermal spray coating, Biomimetics, sol-gel, spray coating and plasma spray coating [18][19][20][21][22][23][24][25]. The EPD method has attracted attention in recent years [25][26].…”

"Investigation of the effect of shot blasting on the surface properties of the HA coatings processed by the EPD method "

“…There are several methods for the coating of metal implant material. These methods are as follows: plasma spray coating, spray coating, electrochemical deposition, electrophoretic deposition (EPD), dip coating, thermal spray coating, sol-gel, and biomimetic method [1,2,[25][26][27][28][29][30][31][32]. EPD has been an attractive method for hydroxyapatite coating processes in recent years [32,33].…”

Influence of Composition and Preparation Conditions on the Structure and Properties of Composite Materials TiO2-SiO2/CaO with a Spherical Particle Shape Based on Tokem-200 Cationic Exchange Resins

“…Great interest in this research has led to the formation of several parallel developing directions: (i) production of dispersed materials, based on synthetic calcium phosphates with its subsequent molding, (ii) development of bioactive glasses, and (iii) development of metal substrates with calcium-phosphate coating. − …”