Oxidation of DL - Methionine by Imidazolium Chlorochromate and Benzimidazolium Chlorochromate in Aqueous Perchlorate Medium

Messé, Mélissa; Bernhard, Chloé; Foppolo, Sophie; Thomas, Lionel; Marchand, Patrice; Herold-Mende, Christel; Idbaih, Ahmed; Kessler, Horst; Etienne-Selloum, Nelly; Ochoa, Charles; Tambar, Uttam K.; Elati, Mohamed; Laquerriere, Patrice; Entz-Werle, Natacha; Martin, Sophie; Reita, Damien; Dontenwill, Monique

doi:10.7598/cst2014.278

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2015

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“…The development of newer Cr(VI) reagents for the oxidation of organic substrates continues to be of interest. In recent years, many such reagents have been developed and used to study the oxidation of various organic compounds [18][19][20][21][22][23][24] .…”

Section: Research Articlementioning

confidence: 99%

Studies on the Kinetics of Benzimidazolium Fluorochromate Oxidation of Pyridine-2-aldehyde in Aqueous Acetic Acid Medium

2015

Chem Sci Trans

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The oxidation of pyridine-2-aldehyde (2-PyA) by benzimidazolium fluorochromate (BIFC) has been studied in aqueous acetic acid medium. The oxidation leads to the formation of the pyridine-2-carboxylic acid. The reaction is first order with respect to [BIFC], [2-PyA] and [H + ] and the reaction is catalyzed by hydrogen ions. The reaction mixture failed to induce the polymerization of added acrylonitrile. The reaction has been studied in different percentage of acetic acid-water mixture. The decrease in dielectric constant of the medium increases the rate of the reaction or low dielectric constant of the medium favours the reactivity. A suitable mechanism has been proposed.

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Section: Research Articlementioning

confidence: 99%

Studies on the Kinetics of Benzimidazolium Fluorochromate Oxidation of Pyridine-2-aldehyde in Aqueous Acetic Acid Medium

2015

Chem Sci Trans

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Oxidation of DL - Methionine by Imidazolium Chlorochromate and Benzimidazolium Chlorochromate in Aqueous Perchlorate Medium

Cited by 1 publication

References 13 publications

Studies on the Kinetics of Benzimidazolium Fluorochromate Oxidation of Pyridine-2-aldehyde in Aqueous Acetic Acid Medium

Studies on the Kinetics of Benzimidazolium Fluorochromate Oxidation of Pyridine-2-aldehyde in Aqueous Acetic Acid Medium

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