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Cited by 114 publications
(111 citation statements)
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“…The peaks in the positive regions are crystalline-dependent, while those in the negative regions are amorphous-dependent. According to the previous studies, [53][54][55] the IR bands at 1458 and 1211 cm À1 , which can be ascribed to the asymmetric CH 3 deformation vibrations (d as CH 3 ) and the asymmetric stretching vibrations of C-O-C groups linked with asymmetric CH 3 rocking vibrations (n as COC + r as CH 3 ), respectively, are conformation-sensitive and represent the interchain interactions. The crystalline-specic band at 920 cm À1 is sensitive to 10 3 helix formation of PLLA a crystals and reveals the intrachain interactions.…”
Section: Time-resolved Ftir Investigation On Isothermal Crystallizationmentioning
confidence: 84%
“…The peaks in the positive regions are crystalline-dependent, while those in the negative regions are amorphous-dependent. According to the previous studies, [53][54][55] the IR bands at 1458 and 1211 cm À1 , which can be ascribed to the asymmetric CH 3 deformation vibrations (d as CH 3 ) and the asymmetric stretching vibrations of C-O-C groups linked with asymmetric CH 3 rocking vibrations (n as COC + r as CH 3 ), respectively, are conformation-sensitive and represent the interchain interactions. The crystalline-specic band at 920 cm À1 is sensitive to 10 3 helix formation of PLLA a crystals and reveals the intrachain interactions.…”
Section: Time-resolved Ftir Investigation On Isothermal Crystallizationmentioning
confidence: 84%
“…To understand the mechanism of CNT induced biopolymer crystallization, FTIR online test method was adopted to analyze the influence of CNTs on the crystallization of biopolymer poly(L-Lactide) and reveal that CNT reinforced biopolymer crystallization is originated from surface induced biopolymer conformational order. (Hu, et al 2009) A recent study also show that CNT could reinforce the piezoelectric actuation performance of regenerated cellulose while the reinforced crystalline is in agreement with it. (Yun, et al 2007).…”
Section: Supramolecular Self-assembly Of Biopolymers Onto Cnt Surfacementioning
confidence: 59%
“…The values of NE larger than 100% in PCL-5k/MWCNTs and MWCNTs-g-PCLs are probably due to the definition, in which the T c s of PCL/MWCNTs nanocomposites (both the blend and grafting polymers) and the neat PCL are compared. However, in the polymer/CNTs blends, polymer chains may interact with CNTs in the melt to form preordered structure [33]. In the MWCNTs-g-PCLs the grafted PCL chains are also stretched.…”
Section: Nucleation Efficiencymentioning
confidence: 99%