Optical Analysis of Ag-NPs Containing Methyl Ammonium Lead Tri-Iodide Thin Films

Mosiori, Cliff Orori; Njoroge, Walter Kamande; Ochoo, Lawrence Otieno

doi:10.22178/pos.26-10

Cited by 2 publications

(1 citation statement)

References 33 publications

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“…Most likely, the increase in the energy gap can be associated with the surface plasmon resonance effect inherent in platinum group metals. Previously, the authors [40] also wrote about an increase in the band gap when adding silver nanoparticles.…”

Section: Sample (Preparation Method)mentioning

confidence: 99%

Bimetallic Pt-IrOx/g-C3N4 Photocatalysts for the Highly Efficient Overall Water Splitting under Visible Light

Sidorenko,

Topchiyan,

Saraev

et al. 2024

Catalysts

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Two series of bimetallic photocatalysts (0.5% Pt/0.01–0.5% IrOx/g-C3N4 and 0.1% Pt/0.01–0.1% IrOx/g-C3N4) were synthesized by the thermolysis of melamine cyanurate and a successive deposition of platinum and iridium labile complexes (Me4N)2[Pt2(μ-OH)2(NO3)8] and fac-[Ir(H2O)3(NO2)3. The synthesized photocatalysts were studied by a set of physicochemical analysis techniques. Platinum exists in two states, with up to 60% in metallic form and the rest in the Pt2+ state, while iridium is primarily oxidized to the Ir3+ state, which was determined by X-ray photoelectron spectroscopy (XPS). The specific surface area (SBET), which is determined by low-temperature nitrogen adsorption, ranges from 80 to 100 m2 g−1 and the band gap energy (Eg) value is in the range of 2.75–2.80 eV as found by diffuse reflectance spectroscopy (DRS). The activity of the photocatalysts was tested in the photocatalytic production of hydrogen from ultrapure water under visible light (λ = 400 nm). It was found that the splitting of water occurs with the formation of the stochiometric amount of H2O2 as an oxidation product. Two photocatalysts 0.5% Pt/0.01% IrOx/g-C3N4 and 0.1% Pt/0.01% IrOx/g-C3N4 showed the highest activity at 100 μmol h−1 gcat−1, which is among the highest in H2 production published for such systems.

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Section: Sample (Preparation Method)mentioning

confidence: 99%