On the Significant Importance of Hg···Cl Spodium Bonding/σ/π-Hole/Noncovalent Interactions and Nanoelectronic/Conductivity Applications in Mercury Complexes: Insights from DFT Spectrum
Suman Hazra,
Dhrubajyoti Majumdar,
Antonio Frontera
et al.
Abstract:This work synthesized two Hg complexes (1−2) using a L O-rich ligand (L O-rich = L O-VAN /L ET-VAN ) in CH 3 OH and CH 3 OH/DCM media. Complex 1 is discrete [(HgCl 2 ) 3 L O-VAN ], while 2 is the coordination polymer (CP) [HgCl 2 L ET-VAN ] n . The complexes were characterized using spectroscopy, SCXRD, HRMS, PXRD, SEM-EDX, and XPS study. The X-ray structure revealed that 1 crystallizes in the monoclinic space group P2 1 /c and is built from isolated trinuclear units of [(HgCl 2 ) 3 L O-VAN ]. Similarly, 2 cry… Show more
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