1999 Abstract:
DOI: 10.1002/(sici)1099-1409(199903)3:3<216::aid-jpp125>3.0.co;2-b
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On the Molecular Stereochemistry of the 21,22,23-trimethyl-5,10,15,20-Tetraphenylporphyrin Cation
Abstract: The crystal structure of the triflate salt of the title compound, [ Me 3 TPP ][ CF 3 SO 3 ], was investigated to obtain structural information on the conformation of N-trimethylated 5,10,15,20-tetraarylporphyrins. The molecular stereochemistry of the cation is characterized by an up/down/up arrangement for the three N-methyl groups with significant pyramidalization at the nitrogen atoms. The macrocycle is severely distorted with an average …
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Cited by 8 publications
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