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Cited by 8 publications
(3 citation statements)
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“…Values of ΔE p for the first reduction are scan-rate independent and vary between 60 and 90 mV, which is not atypical. 96 In the case of 5, the first reduction process (−1.17 V) is quasireversible; on the basis of the redox chemistry of the free ligand and other nitroaromatics, 63,99,100 we cannot exclude the possibility that this process involves reduction of the nitro group. In all cases, the second reduction process is chemically irreversible.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Values of ΔE p for the first reduction are scan-rate independent and vary between 60 and 90 mV, which is not atypical. 96 In the case of 5, the first reduction process (−1.17 V) is quasireversible; on the basis of the redox chemistry of the free ligand and other nitroaromatics, 63,99,100 we cannot exclude the possibility that this process involves reduction of the nitro group. In all cases, the second reduction process is chemically irreversible.…”
Section: ■ Introductionmentioning
confidence: 99%
“…In the last two decades, we have focused our research interests on the study of the photochemical and morphological properties of Re­(I) polymeric complexes. The polymers used in our works have been derived from the P4VP backbone, and they contain fac -XRe­(CO) 3 L pendants in their structure. The Re­(I) polymers are polyelectrolytes where Re­(I) center coordinates one of every three pyridines present in the P4VP. They display interesting as well as intriguing features both in photochemistry and in material science.…”
Section: Introductionmentioning
confidence: 99%
“…Mostrando en ambos casos, la absorción de la especie reducida aproximadamente a 410 nm como se puede ver en la figura 10. Espectro en presencia de N 2 , reacción directa del esolv y PV-5N mediante radiólisis de pulso (Bracco, L.L.B. et al, 2011).…”
Section: •-unclassified